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J. Am. Chem. Soc., 132, ASAP (2010)

76. Nine-Step Enantioselective Total Synthesis of (–)-Vincorine
B. D. Horning, D. W. C. MacMillan
J. Am. Chem. Soc., ASAP (2013)

Nine-Step Enantioselective Total Synthesis of (–)-Vincorine

Science

75. Photoredox Activation for the Direct β-Arylation of Ketones and Aldehydes
M. T. Pirnot, D. A. Rankic, D. B. C. Martin, D. W. C. MacMillan
Science, 339, 1593-1596 (2013)

Photoredox Activation for the Direct β-Arylation of Ketones and Aldehydes

Chem. Rev.

74. Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
C. K. Prier, D. A. Rankic, D. W. C. MacMillan
Chem. Rev., ASAP, (2013)

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

J. Am. Chem. Soc., 132, ASAP (2010)

73. Enantioselective Organo-SOMO Cycloadditions: A Catalytic Approach to Complex Pyrrolidines from Olefins and Aldehydes
N. T. Jui, J. A. O. Garber, F. G. Finelli, D. W. C. MacMillan
J. Am. Chem. Soc., 134, 11400-11403 (2012)

SOMO-Pyrrolidines

J. Am. Chem. Soc., 132, ASAP (2010)

72. Enantioselective Copper-Catalyzed Construction of Aryl Pyrroloindolines via an Arylation–Cyclization Cascade
S. Zhu, D. W. C. MacMillan
J. Am. Chem. Soc., 134, 10815-10818 (2012)

Enantioselective Copper-Catalyzed Construction of Aryl Pyrroloindolines via an Arylation–Cyclization Cascade

J. Am. Chem. Soc., 132, ASAP (2010)

71. Enantioselective α-Vinylation of Aldehydes via the Synergistic Combination of Copper and Amine Catalysis
E. Skucas, D. W. C. MacMillan
J. Am. Chem. Soc., 134, 9090-9093 (2012)

Enantioselective α-Vinylation of Aldehydes via the Synergistic Combination of Copper and Amine Catalysis

Chemical Science

70. Synergistic catalysis: A powerful synthetic strategy for new reaction development
A. E. Allen, D. W. C. MacMillan
Chem. Sci., 3, 633-658 (2012)

Synergistic catalysis: A powerful synthetic strategy for new reaction development

Chemical Science

69. A general approach to the enantioselective α-oxidation of aldehydes via synergistic catalysis
S. P. Simonovich, J. F. Van Humbeck, D. W. C. MacMillan
Chem. Sci., 3, 58-61 (2012)

A general approach to the enantioselective α-oxidation of aldehydes via synergistic catalysis

Nature2011

68. Trifluoromethylation of Arenes and Heteroarenes by Means of Photoredox Catalysis
D. A. Nagib, D. W. C. MacMillan
Nature, 480, 224-228 (2011)

Arene Trifluoromethylation

Science 2011 (334)

67. Discovery of an α-Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity
A. McNally, C. K. Prier, D. W. C. MacMillan
Science, 334, 1114-1117 (2011)

Discovery of an α-Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity

J. Am. Chem. Soc., 132, ASAP (2010)

66. Enantioselective α-Arylation of Carbonyls via Cu(I)-Bisoxazoline Catalysis
J. S. Harvey, S. P. Simonovich, C. R. Jamison, D. W. C. MacMillan
J. Am. Chem. Soc., 133, 13782-13785 (2011)

Enantioselective r-Arylation of Carbonyls via Cu(I)-Bisoxazoline Catalysis

Nature2011

65. Collective synthesis of natural products by means of organocascade catalysis
S. B. Jones, B. Simmons, A. Mastracchio, D. W. C. MacMillan
Nature, 475, 183-188 (2011)

Collective Synthesis of Natural Products by means of Organocascade Catalysis

Angewandte Cover

64. Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α-Trifluoromethyl Carbonyl Compounds
P. V. Pham, D. A. Nagib, D. W. C. MacMillan
Angew. Chem. Int. Ed., 50, 6119-6122 (2011)

Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α-Trifluoromethyl Carbonyl Compounds

Chemical Science

63. The intramolecular asymmetric allylation of aldehydes via organo-SOMO catalysis: A novel approach to ring construction
P. V. Pham, K. Ashton, D. W. C. MacMillan
Chem. Sci., 2, 1470-1473 (2011)

The intramolecular asymmetric allylation of aldehydes via organo-SOMO catalysis: A novel approach to ring construction

J. Am. Chem. Soc., 132, ASAP (2010)

62. Enantioselective α-Arylation of Aldehydes via the Productive Merger of Iodonium Salts and Organocatalysis
A. Allen, D. W. C. MacMillan
J. Am. Chem. Soc., 133, 4260-4263 (2011)

Enantioselective α-Arylation of Aldehydes via the Productive Merger of Iodonium Salts and Organocatalysis

J. Am. Chem. Soc., 132, ASAP (2010)

61. Enantioselective Organocatalytic α-Fluorination of Cyclic Ketones
P. Kwiatkowski, T. D. Beeson, J. C. Conrad, D. W. C. MacMillan
J. Am. Chem. Soc., 133, 1738-1741 (2011)

Ketone Fluorination

Chemical Science

60. Total synthesis of diazonamide A
R. R. Knowles, J. Carpenter, S. B. Blakey, A. Kayano, I. K. Mangion, C. J. Sinz , D. W. C. MacMillan
Chem. Sci., 2, 308-311 (2011)

Total synthesis of diazonamide A

59. The Preparation of (2R,5S)-2-t-Butyl-3,5-dimethylimidazolidin-4-one
T. H. Graham, B. D. Horning, D. W. C. MacMillan
Org. Synth., 88, 42-53 (2011)

The Preparation of (2R,5S)-2-t-Butyl-3,5-dimethylimidazolidin-4-one

PNAS - Special Issue

58. Direct and enantioselective α-allylation of ketones via singly occupied molecular orbital (SOMO) catalysis
A. Mastracchio, A. A. Warkentin, A. M. Walji, D. W. C. MacMillan
Proc. Nat. Acad. Sci. USA, 107, 20648-20651 (2010)
** Special issue on organocatalysis

Direct and enantioselective α-allylation of ketones via singly occupied molecular orbital (SOMO) catalysis

J. Am. Chem. Soc., 132, ASAP (2010)

57. Enantioselective α-Benzylation of Aldehydes via Photoredox Organocatalysis
H.-W. Shih, M. N. Vander Wal, R. L. Grange, D. W. C. MacMillan
J. Am. Chem. Soc., 132, 13600-13603 (2010)

Enantioselective α-Benzylation of Aldehydes via Photoredox Organocatalysis

Angew. Chem. Int. Ed., 49, ASAP (2010)

56. Mechanistic Complexity in Organo-SOMO Activation
J. J. Devery III, J. C. Conrad, D. W. C. MacMillan, R. A. Flowers II
Angew. Chem. Int. Ed., 49, 6106-6110 (2010)

Mechanistic Complexity in Organo-SOMO Activation

J. Am. Chem. Soc., 132, ASAP (2010)

55. Enantioselective Organo-SOMO Cascade Cycloadditions:
A Rapid Approach to Molecular Complexity from Simple Aldehydes and Olefins
N. T. Jui, E. C. Y. Lee, D. W. C. MacMillan
J. Am. Chem. Soc., 132, 10015-10017 (2010)

Mechanistic Complexity in Organo-SOMO Activation

J. Am. Chem. Soc., 132, ASAP (2010)

54. Concerning the Mechanism of the FeCl₃-Catalyzed α-Oxyamination of Aldehydes:
Evidence for a Non-SOMO Activation Pathway
J. F. Van Humbeck, S. P. Simonovich, R. R. Knowles, D. W. C. MacMillan
J. Am. Chem. Soc., 132, 10012-10014 (2010)

Concerning the Mechanism of the FeCl3-Catalyzed α-Oxyamination of Aldehydes: Evidence for a Non-SOMO Activation Pathway

Chemical Science

53. The organocatalytic three-step total synthesis of (+)-frondosin B
M. Reiter, S. Torssell, S. Lee, D. W. C. MacMillan
Chem. Sci., 1, 37-42 (2010)

The organocatalytic three-step total synthesis of (+)-frondosin B

J. Am. Chem. Soc., 132, ASAP (2010)

52. Nature of Intermediates in Organo-SOMO Catalysis of α-Arylation of Aldehydes
J. M. Um, O. Gutierrez, F. Schoenebeck, K. N. Houk, D. W. C. MacMillan
J. Am. Chem. Soc., 132, 6106-6110 (2010)

Nature of Intermediates in Organo-SOMO Catalysis of α-Arylation of Aldehydes

J. Am. Chem. Soc., 132, ASAP (2010)

51. Enantioselective Polyene Cyclization via Organo-SOMO Catalysis
S. Rendler, D. W. C. MacMillan
J. Am. Chem. Soc., 132, 5027-5029 (2010)

Enantioselective Polyene Cyclization via Organo-SOMO Catalysis

J. Am. Chem. Soc., 132, ASAP (2010)

50. The Productive Merger of Iodonium Salts and Organocatalysis:
A Non-photolytic Approach to the Enantioselective α-Trifluoromethylation of Aldehydes
A. E. Allen, D. W. C. MacMillan
J. Am. Chem. Soc., 132, 4986-4987 (2010)

The Productive Merger of Iodonium Salts and Organocatalysis: A Non-photolytic Approach to the Enantioselective α-Trifluoromethylation of Aldehydes

J. Am. Chem. Soc., 132, ASAP (2010)

49. Nine-Step Enantioselective Total Synthesis of (+)-Minfiensine
S. B. Jones, B. Simmons, D. W. C. MacMillan
J. Am. Chem. Soc., 131, 13606-13607 (2009)

Nine-Step Enantioselective Total Synthesis of (+)-Minfiensine

Tetrahedron

48. Development of a General, Enantioselective Organocatalytic Mukaiyama-Michael Reaction
with α,β-Unsaturated Aldehydes
C. J. Borths, D. E. Carrera, D. W. C. MacMillan
Tetrahedron, 65, 6746-6753 (2009) ** Tetrahedron Prize for Creativity in Organic Chemistry, Larry Overman.

Development of a General, Enantioselective Organocatalytic Mukaiyama-Michael Reaction with α,β-Unsaturated Aldehydes

J. Am. Chem. Soc., 132, ASAP (2010)

47. Enantioselective Aldehyde α-Nitroalkylation via Oxidative Organocatalysis
J. E. Wilson, A. D. Casarez, D. W. C. MacMillan
J. Am. Chem. Soc., 131, 11332-11334 (2009)

Enantioselective Aldehyde α-Nitroalkylation via Oxidative Organocatalysis

J. Am. Chem. Soc., 132, ASAP (2010)

46. Enantioselective α-Arylation of Aldehydes via Organo-SOMO Catalysis.
An Ortho-Selective Arylation Reaction Based on an Open-Shell Pathway
J. C. Conrad, J. Kong, B. N. Laforteza, D. W. C. MacMillan
J. Am. Chem. Soc., 131, 11640-11641 (2009)

Enantioselective α-Arylation of Aldehydes via Organo-SOMO Catalysis. An Ortho-Selective Arylation Reaction Based on an Open-Shell Pathway

J. Am. Chem. Soc., 132, ASAP (2010)

45. Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis
D. A. Nagib, M. E. Scott, D. W. C. MacMillan
J. Am. Chem. Soc., 131, 10875-10877 (2009)

Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis

Angew

44. Enantioselective Linchpin Catalysis by SOMO Catalysis: An Approach to the
Asymmetric α-Chlorination of Aldehydes and Terminal Epoxide Formation
M. Amatore, T. D. Beeson, S. P. Brown, D. W. C. MacMillan
Angew. Chem. Int. Ed., 48, 5121-5124 (2009)

Enantioselective Linchpin Catalysis by SOMO Catalysis: An Approach to the Asymmetric α-Chlorination of Aldehydes and Terminal Epoxide Formation

Angew. Chem. Int. Ed., 49, ASAP (2010)

43. Cycle-Specific Organocascade Catalysis: Application to Olefin Hydroamination,
Hydro-oxidation, and Amino-oxidation, and to Natural Product Synthesis
B. Simmons, A. Walji, D. W. C. MacMillan
Angew. Chem. Int. Ed., 48, 4349-4353 (2009)

Cycle-Specific Organocascade Catalysis: Application to Olefin Hydroamination, Hydro-oxidation, and Amino-oxidation, and to Natural Product Synthesis

Tetrahedron

42. A process for the rapid removal of dialkylamino-substituents from aromatic rings.
Application to the expedient synthesis of (R)-tolterodine
N. Paras, B. Simmons, D. W. C. MacMillan
Tetrahedron, 65, 3232-3238 (2009) ** Tetrahedron Young Investigator Award, Justin Du Bois.

A process for the rapid removal of dialkylamino-substituents from aromatic rings. Application to the expedient synthesis of (R)-tolterodine

J. Am. Chem. Soc., 132, ASAP (2010)

41. Enantioselective Organo-SOMO Catalysis: The Carbo-oxidation of Styrenes
T. H. Graham, C. M. Jones, N. T. Jui, D. W. C. MacMillan
J. Am. Chem. Soc., 130, 16494-16495 (2008)

Enantioselective Organo-SOMO Catalysis: The Carbo-oxidation of Styrenes

Nature

40. The Advent and Development of Organocatalysis
D. W. C. MacMillan
Nature 455, 304-308 (2008)

The Advent and Development of Organocatalysis

Science

39. Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes
D. Nicewicz, D. W. C. MacMillan
Science, 322, 77-80 (2008)

Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes

Angew

38. Total Synthesis and Structural Revision of Callipeltoside C
J. Carpenter, A. B. Northrup, d. M. Chung, J. J. M. Wiener, S.-G. Kim, D. W. C. MacMillan
Angew. Chem. Int. Ed., 47, 3568-3572 (2008)

Total Synthesis and Structural Revision of Callipeltoside C

J. Am. Chem. Soc., 132, ASAP (2010)

37. Enantioselective Organo-SOMO Catalysis: The α-Vinylation of Aldehydes
H. Kim, D. W. C. MacMillan
J. Am. Chem. Soc., 130, 398-399 (2008)

Enantioselective Organo-SOMO Catalysis: The α-Vinylation of Aldehydes

Acc. Chem. Res.

36. Enantioselective Organocatalytic Transfer Hydrogenation Reactions using Hantzsch Esters
S. G. Ouellet, A. Walji, D. W. C. MacMillan
Acc. Chem. Res., 40, 1327-1339 (2007) ** Special issue on hydrogenation & transfer hydrogenation

Enantioselective Organocatalytic Transfer Hydrogenation Reactions using Hantzsch Esters

J. Am. Chem. Soc., 132, ASAP (2010)

35. Organocatalytic Vinyl and Friedel-Crafts Alkylations with Trifluoroborate Salts
S. Lee, D. W. C. MacMillan
J. Am. Chem. Soc., 129, 15438-15439 (2007)

Organocatalytic Vinyl and Friedel−Crafts Alkylations with Trifluoroborate Salts

SynLett

34. Strategies to Bypass the Taxol Problem: Enantioselective Cascade Catalysis,
A New Approach for the Efficient Construction of Molecular Complexity
A. Walji, D. W. C. MacMillan
Syn. Lett., 10, 1477-1489 (2007)

Strategies to Bypass the Taxol Problem: Enantioselective Cascade Catalysis, A New Approach for the Efficient Construction of Molecular Complexity A. Walji, D. W. C. MacMillan

J. Am. Chem. Soc., 132, ASAP (2010)

33. Enantioselective Organocatalytic Singly Occupied Molecular Orbital Activation: The Enantioselective a-Enolation of Aldehydes
H. Jang, J. Hong, D. W. C. MacMillan
J. Am. Chem. Soc., 129, 7004-7005 (2007)

Enantioselective Organocatalytic Singly Occupied Molecular Orbital Activation: The Enantioselective a-Enolation of Aldehydes

Science07

32. Enantioselective Organocatalysis Using SOMO Activation
T. D. Beeson, A. Mastracchio, J. Hong, K. Ashton, D. W. C. MacMillan
Science, 316, 582-585 (2007)

Enantioselective Organocatalysis Using SOMO Activation

J. Am. Chem. Soc., 132, ASAP (2010)

31. Organocatalytic Transfer Hydrogenation of Cyclic Enones
J. B. Tuttle, S. G. Ouellet, D. W. C. MacMillan
J. Am. Chem. Soc., 128, 12662-12663 (2006)

Organocatalytic Transfer Hydrogenation of Cyclic Enones

Tetrahedron

30. Enantioselective Organocatalytic Epoxidation Using Hypervalent Iodine Reagents
S. Lee, D. W. C. MacMillan
Tetrahedron, 62, 11413-11424 (2006) ** Tetrahedron Young Investigator Award, David MacMillan.

Enantioselective Organocatalytic Epoxidation Using Hypervalent Iodine Reagents

J. Am. Chem. Soc., 132, ASAP (2010)

29. Enantioselective Organocatalytic Amine Conjugate Addition
Y. K. Chen, M. Yoshida, D. W. C. MacMillan
J. Am. Chem. Soc., 128, 9328-9329 (2006)

Enantioselective Organocatalytic Amine Conjugate Addition

Aldrich

28. Modern Strategies in Organic Catalysis: The Advent and Development of Iminium Activation
G. Lelais, D. W. C. MacMillan
Aldrichimica Acta, 39, 79-87 (2006)

Modern Strategies in Organic Catalysis: The Advent and Development of Iminium Activation

J. Am. Chem. Soc., 132, ASAP (2010)

27. Enantioselective Organocatalytic Reductive Amination
R. I. Storer, D. E. Carrera, Y. Ni, D. W. C. MacMillan
J. Am. Chem. Soc., 128, 84-86 (2006)

Enantioselective Organocatalytic Reductive Amination

J. Am. Chem. Soc., 132, ASAP (2010)

26. Enantioselective Organo-Cascade Catalysis
Y. Huang, A. M. Walji, C. H. Larsen, D. W. C. MacMillan
J. Am. Chem. Soc., 127, 15051-15053 (2005)

Enantioselective Organo-Cascade Catalysis

J. Am. Chem. Soc., 132, ASAP (2010)

25. Enantioselective Organocatalytic Intramolecular Diels-Alder Reaction.
The Asymmetric Synthesis of Solanapyrone D
R. M. Wilson, W. S. Jen, D. W. C. MacMillan
J. Am. Chem. Soc., 127, 11616-11617 (2005)

Enantioselective Organocatalytic Intramolecular Diels-Alder Reaction. The Asymmetric Synthesis of Solanapyrone D

J. Am. Chem. Soc., 132, ASAP (2010)

24. Enantioselective Organocatalytic Direct α-Fluorination
T. D. Beeson, D. W. C. MacMillan
J. Am. Chem. Soc., 127, 8826-8828 (2005)

Enantioselective Organocatalytic Direct α-Fluorination

J. Am. Chem. Soc., 132, ASAP (2010)

23. Total Synthesis of Brasoside and Littoralisone
I. K. Mangion, D. W. C. MacMillan
J. Am. Chem. Soc., 127, 3696-3697 (2005)

Total Synthesis of Brasoside and Littoralisone

J. Am. Chem. Soc., 132, ASAP (2010)

22. Enantioselective Organocatalytic Cyclopropanations. The Identification of a
New Class of Iminium Catalyst Based Upon Directed Electrostatic Activations
R. K. Kunz, D. W. C. MacMillan
J. Am. Chem. Soc., 127, 3240-3241 (2005)

Enantioselective Organocatalytic Cyclopropanations. The Identification of a New Class of Iminium Catalyst Based Upon Directed Electrostatic Activations

J. Am. Chem. Soc., 132, ASAP (2010)

21. Enantioselective Organocatalytic Hydride Reduction
S. G. Ouellet, J. B. Tuttle, D. W. C. MacMillan
J. Am. Chem. Soc., 127, 32-33 (2005)

Enantioselective Organocatalytic Hydride Reduction

Angew. Chem. Int. Ed., 49, ASAP (2010)

20. Importance of Iminium Geometry Control in Enamine Catalysis:
Identification of a New Catalyst Architecture for Aldehyde-Aldehyde Couplings
I. K. Mangion, A. B. Northrup, D. W. C. MacMillan
Angew. Chem. Int. Ed., 43, 6722-6724 (2004)

Importance of Iminium Geometry Control in Enamine Catalysis: Identification of a New Catalyst Architecture for Aldehyde-Aldehyde Couplings

Science

19. Two Step Synthesis of Carbohydrates by Selective Aldol Reactions
A. B. Northrup, D. W. C. MacMillan
Science, 305, 1752-1755 (2004)

Two Step Synthesis of Carbohydrates by Selective Aldol Reactions

Tetrahedron

18. Enantioselective Organocatalytic Aldehyde-Aldehyde Cross-Aldol Couplings.
The Broad Utility of a-Thioacetal Aldehydes
R. I. Storer, D. W. C. MacMillan
Tetrahedron, 60, 7705-7714 (2004) ** Tetrahedron Prize for Creativity in Organic Chemistry, Dieter Seebach.

Enantioselective Organocatalytic Aldehyde-Aldehyde Cross-Aldol Couplings. The Broad Utility of a-Thioacetal Aldehydes

Proc. Nat. Acad. Sci. USA

17. Enantioselective Organocatalytic Construction of Pyrroloindolines by a Cascade
Addition-Cyclization Strategy: Synthesis of (-)-flustramine B (Issue Cover)
J. F. Austin, S. G. Kim, C. J. Sinz, W. J. Xiao, D. W. C. MacMillan
Proc. Nat. Acad. Sci. USA, 101, 5482-5487 (2004)

Enantioselective Organocatalytic Construction of Pyrroloindolines by a Cascade Addition-Cyclization Strategy: Synthesis of (-)-flustramine B

Angew. Chem. Int. Ed.

16. Enantioselective Organocatalytic Direct Aldol Reaction of a-Oxyladehydes:
Step One in a Two-Step Synthesis of Carbohydrates
A. B. Northrup, I. K. Mangion, F. Hettche, D. W. C. MacMillan
Angew. Chem. Int. Ed., 43, 2152-2154 (2004)

Enantioselective Organocatalytic Direct Aldol Reaction of a-Oxyladehydes: Step One in a Two-Step Synthesis of Carbohydrates

J. Am. Chem. Soc., 132, ASAP (2010)

15. The Direct and Enantioselective Organocatalytic α-Chlorination of Aldehydes
M. P. Brochu, S. P. Brown, D. W. C. MacMillan
J. Am. Chem. Soc., 126, 4108-4109 (2004)

The Direct and Enantioselective Organocatalytic α-Chlorination of Aldehydes

J. Am. Chem. Soc., 132, ASAP (2010)

14. The Direct and Enantioselective Organocatalytic α-Oxidation of Aldehydes
S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan
J. Am. Chem. Soc., 125, 10808-10809 (2003)

The Direct and Enantioselective Organocatalytic α-Oxidation of Aldehydes

J. Am. Chem. Soc., 132, ASAP (2010)

13. The First Suzuki Cross-Coupling of Aryltrimethylammonium Ions
S. B. Blakey, D. W. C. MacMillan
J. Am. Chem. Soc., 125, 6046-6047 (2003)

The First Suzuki Cross-Coupling of Aryltrimethylammonium Ions

J. Am. Chem. Soc., 132, ASAP (2010)

12. The First Enantioselective Organocatalytic Mukaiyama-Michael Reaction:
A Direct Method for the Synthesis of Enantioenriched γ-Butenolide Architecture
S. P. Brown, N. C. Goodwin, D. W. C. MacMillan
J. Am. Chem. Soc., 125, 1192-1194 (2003)

The First Enantioselective Organocatalytic Mukaiyama-Michael Reaction: A Direct Method for the Synthesis of Enantioenriched γ-Butenolide Architecture

J. Am. Chem. Soc., 132, ASAP (2010)

11. Development of a New Lewis Acid-Catalyzed [3,3]-Sigmatropic Rearrangement: The Allenoate-Claisen Rearrangement
T. H. Lambert, D. W. C. MacMillan
J. Am. Chem. Soc., 124, 13646-13647 (2002)

Development of a New Lewis Acid-Catalyzed [3,3]-Sigmatropic Rearrangement: The Allenoate-Claisen Rearrangement

J. Am. Chem. Soc., 132, ASAP (2010)

10. The Enantioselective Organocatalytic 1,4-Addition of Electron Rich Benzenes to α,β-Unsaturated Aldehydes
N. A. Paras, D. W. C. MacMillan
J. Am. Chem. Soc., 124, 7894-7895 (2002)

The Enantioselective Organocatalytic 1,4-Addition of Electron Rich Benzenes to α,β-Unsaturated Aldehydes

J. Am. Chem. Soc., 132, ASAP (2010)

9. The First Direct and Enantioselective Cross-Aldol Reactions of Aldehydes
A. B. Northrup, D. W. C. MacMillan
J. Am. Chem. Soc., 124, 6798-6799 (2002)

The First Direct and Enantioselective Cross-Aldol Reactions of Aldehydes

J. Am. Chem. Soc., 132, ASAP (2010)

8. The First General Enantioselective Catalytic Diels-Alder Reaction with Simple α,β-Unsaturated Ketones
A. B. Northrup, D. W. C. MacMillan
J. Am. Chem. Soc., 124, 2458-2460 (2002)

The First General Enantioselective Catalytic Diels-Alder Reaction with Simple α,β-Unsaturated Ketones

J. Am. Chem. Soc., 132, ASAP (2010)

7. Enantioselective Indole Alkylations. Design of a New and Highly Effective Chiral Amine for Iminuim Catalysis
J. F. Austin, D. W. C. MacMillan
J. Am. Chem. Soc., 124, 1172-1173 (2002)

Enantioselective Indole Alkylations. Design of a New and Highly Effective Chiral Amine for Iminuim Catalysis

J. Am. Chem. Soc., 132, ASAP (2010)

6. New Strategies in Organocatalysis: The First Enantioselective Organocatalytic Friedel-Crafts Alkylation
N. A. Paras, D. W. C. MacMillan
J. Am. Chem. Soc., 123, 4370-4371 (2001)

New Strategies in Organocatalysis: The First Enantioselective Organocatalytic Friedel-Crafts Alkylation

J. Am. Chem. Soc., 132, ASAP (2010)

5. Enantioselective Claisen Rearrangements: Development of a First Generation Asymmetric Acyl-Claisen Rearrangement
T. P. Yoon, D. W. C. MacMillan
J. Am. Chem. Soc., 123, 2911-2912 (2001)

Design of a New Cascade Reaction for the Construction of Complex Acyclic Structure: The Tandem Acyl-Claisen Rearrangement

J. Am. Chem. Soc., 132, ASAP (2010)

4. Design of a New Cascade Reaction for the Construction of Complex Acyclic Structure: The Tandem Acyl-Claisen Rearrangement
V. M. Dong, D. W. C. MacMillan
J. Am. Chem. Soc., 123, 2448-2449 (2001)

Design of a New Cascade Reaction for the Construction of Complex Acyclic Structure: The Tandem Acyl-Claisen Rearrangement

J. Am. Chem. Soc., 132, ASAP (2010)

3. New Strategies for Organic Synthesis: The First Enantioselective Organocatalytic 1,3-Dipolar Cycloaddition
W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan
J. Am. Chem. Soc., 121, 9874-9875 (2000)

New Strategies for Organic Synthesis: The First Enantioselective Organocatalytic 1,3-Dipolar Cycloaddition

J. Am. Chem. Soc., 132, ASAP (2010)

2. New Strategies for Organic Synthesis: The First Highly Enantioselective Organocatalytic Diels-Alder Reaction
K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan
J. Am. Chem. Soc., 122, 4243-4244 (2000)

New Strategies for Organic Synthesis: The First Highly Enantioselective Organocatalytic Diels-Alder Reaction

J. Am. Chem. Soc., 132, ASAP (2010)

1. Development of a New Lewis Acid-Catalyzed Claisen Rearrangement
T. P. Yoon, V. M. Dong, D. W. C. MacMillan
J. Am. Chem. Soc., 121, 9726-9727 (1999)

Development of a New Lewis Acid-Catalyzed Claisen Rearrangement