Multimedia: Featured
Putting the squeeze on batteries
Posted November 21, 2011; 12:00 p.m.
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Professor Craig Arnold is working to make lithium-ion batteries last longer and provide more energy. Read more.
Video Closed Captions
[music]
Craig Arnold:
Cars, cell phones, laptops.
Craig Arnold:
We all rely on batteries every day.
Craig Arnold:
My name is Craig Arnold.
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And I want to make better batteries.
Craig Arnold:
Lithium-ion batteries are good.
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But we all know that they tend
to lose their capacity over
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time, and they don't last forever.
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Batteries are complex.
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They're made up of many layers of different materials.
Craig Arnold:
If we take these layers apart, we could see the dark
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electrode material and we could see the
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white separator membrane.
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This membrane keeps the
electrodes from touching each
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other in this tight pack.
Craig Arnold:
In my lab, we try to simulate
what happens to the separator
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membrane over its lifetime.
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We roll up the material and
expose it to high pressures.
Craig Arnold:
On a microscopic level, this has effects
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similar to years of use.
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These mechanical stresses can cause
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changes to the separator.
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But what does that have to do
with your battery failing?
Craig Arnold:
Well, let me explain.
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Here's an ordinary sponge.
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You'll notice it has a bunch of holes in
it to allow water to pass through.
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If I were to press on it, it
would close these holes and
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prevent water from passing through the sponge.
Craig Arnold:
This is not unlike the battery separator.
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In this material, there is also a lot
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of little tiny holes.
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If I were to squeeze it, these
holes would also close up,
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preventing lithium ions from
passing through the membrane.
[music]
Craig Arnold:
We can see these holes if we
use an electron microscope
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with high magnification.
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In a new separator, the holes
are all over the membrane,
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allowing lithium ions to easily pass.
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After simulating long-time use
and storage, we can see the
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holes disappearing from the
membrane, making it more
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difficult for lithium ions to pass.
Craig Arnold:
So, what can we do about this?
Craig Arnold:
One way to fix this is to prevent
the pores from closing up.
Craig Arnold:
Imagine a battery separator
that's strong enough to resist
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mechanical stress.
Craig Arnold:
So in fact, batteries are not
just electrochemical devices.
Craig Arnold:
Their mechanical properties
can also affect their performance.
Craig Arnold:
By better understanding the
science of batteries, we can
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begin to engineer ways to keep
the current flowing longer.
Craig Arnold:
Boy, I could really use
that in my smartphone.
Photographer:
Hey, Craig.
That was fun. [laughter]






