Amorphous solid

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In condensed matter physics, an amorphous or non-crystalline solid is a solid that lacks the long-range order characteristic of a crystal.

In part of the older literature, the term has been used synonymous with glass. Nowadays, "amorphous solid" is considered to be the overarching concept, and "glass" the more special case: A glass is an amorphous solid that transforms into a liquid upon heating through the glass transition.[1]

Other types of amorphous solids include gels, thin films, and nanostructured materials.


Nanostructured materials

It is difficult to make a distinction between truly amorphous solids and crystalline solids if the size of the crystals is very small. Even amorphous materials have some short-range order at the atomic length scale due the nature of chemical bonding. Furthermore, in very small crystals a large fraction of the atoms are located at or near the surface of the crystal; relaxation of the surface and interfacial effects distort the atomic positions, decreasing the structural order. Even the most advanced structural characterization techniques, such as x-ray diffraction and transmission electron microscopy, have difficulty in distinguishing between amorphous and crystalline structures on these length scales.

Amorphous thin films

Amorphous phases are important constituents of thin films, which are solid layers of a few nm to some tens of ┬Ám thickness deposited upon an underlying substrate. So-called structure zone models were developed to describe the microstructure and ceramics of thin films as a function of the homologeous temperature Th that is the ratio of deposition temperature over melting temperature.[2][3] According to these models, a necessary (but not sufficient) condition for the occurrence of amorphous phases is that Th has to be smaller than 0.3, that is the deposition temperature must be below 30% of the melting temperature. For higher values, the surface diffusion of deposited atomic species would allow for the formation of crystallites with long range atomic order.

Regarding their applications, amorphous metallic layers played an important role in the discussion of a suspected superconductivity in amorphous metals.[4] Today, optical coatings made from TiO2, SiO2, Ta2O5 etc. and combinations of them in most cases consist of amorphous phases of these compounds. Much research is carried out into thin amorphous films as a gas separating membrane layer.[5] The technologically most important thin amorphous film is probably represented by few nm thin SiO2 layers serving as isolator above the conducting channel of a metal-oxide semiconductor field-effect transistor (MOSFET). Also, hydrogenated amorphous silicon, a-Si:H in short, is of technical significance for thin film solar cells. In case of a-Si:H the missing long-range order between silicon atoms is partly induced by the presence by hydrogen in the percent range.

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