Diatomic molecule

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Diatomic molecules are molecules composed only of two atoms, of either the same or different chemical elements. The prefix di- means two in Greek. Common diatomic molecules are hydrogen (H2), nitrogen (N2), oxygen (O2), and carbon monoxide (CO). Seven elements exist in the diatomic state in the liquid and solid forms: H2, N2, O2, F2, Cl2, Br2, and I2. Most elements (and many chemical compounds) aside from the form diatomic molecules when evaporated, although at very high temperatures, all materials disintegrate into atoms. The noble gases do form diatomic molecules.

Contents

Occurrence

Hundreds of diatomic molecules have been characterized[1] in the terrestrial environment, laboratory, and interstellar medium. About 99% of the Earth's atmosphere is composed of diatomic molecules, specifically oxygen and nitrogen at 21 and 78%, respectively. The natural abundance of hydrogen (H2) in the Earth's atmosphere is only on the order of parts per million, but H2 is, in fact, the most abundant diatomic molecule seen in nature. The interstellar medium is, indeed, dominated by hydrogen atoms.

Elements that consist of diatomic molecules, under typical laboratory conditions of 1 bar and 25 °C, include hydrogen (H2), nitrogen (N2), oxygen (O2), and the halogens.[2] Again, many other diatomics are possible and form when elements are evaporated, but these diatomic species repolymerize at lower temperatures. For example, heating ("cracking") elemental phosphorus gives diphosphorus.

If a diatomic molecule consists of two atoms of the same element, such as H2 and O2, then it is said to be homonuclear, but otherwise it is heteronuclear, such as with CO or NO. The bond in a homonuclear diatomic molecule is non-polar and covalent. In most diatomic molecules, the elements are nonidentical. Prominent examples include carbon monoxide, nitric oxide, and hydrogen chloride, but other important examples include MgO and NaCl.

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