Ionization is the physical process of converting an atom or molecule into an ion by adding or removing charged particles such as electrons or other ions. This is often confused with dissociation (chemistry).
The process works slightly differently depending on whether an ion with a positive or a negative electric charge is being produced. A positively-charged ion is produced when an electron bonded to an atom (or molecule) absorbs enough energy to escape from the electric potential barrier that originally confined it, thus breaking the bond and freeing it to move. The amount of energy required is called the ionization potential. A negatively-charged ion is produced when a free electron collides with an atom and is subsequently caught inside the electric potential barrier, releasing any excess energy.
In general, ionization can be broken down into two types: sequential ionization and non-sequential ionization. In classical physics, only sequential ionization can take place; refer to the Classical ionization section for more information. Non-sequential ionization violates several laws of classical physics; refer to the Quantum ionization section.
Applying only classical physics and the Bohr model of the atom makes both atomic and molecular ionization entirely deterministic; that is, every problem will always have a definite and computable answer. According to classical physics, it is absolutely necessary that the energy of the electron exceeds the energy difference of the potential barrier it is trying to pass. In concept, this idea should make sense: The same way a person cannot jump over a one-meter wall without jumping at least one meter off the ground, an electron cannot get over a 13.6-eV potential barrier without at least 13.6 eV of energy.
Applying to positive ionization
According to these two principles, the energy required to release an electron is strictly greater than or equal to the potential difference between the current bound atomic or molecular orbital and the highest possible orbital. If the energy absorbed exceeds this potential, then the electron is emitted as a free electron. Otherwise, the electron briefly enters an excited state until the energy absorbed is radiated out and the electron re-enters the lowest available state.
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