Specific heat capacity

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Heat capacity (usually denoted by a capital C, often with subscripts) is the measurable physical quantity that characterizes the amount of heat required to change a body's temperature by a given amount. In the International System of Units, heat capacity is expressed in units of joules per kelvin.

Derived quantities that specify heat capacity as an intensive property, independent of the size of a sample, are the molar heat capacity, which is the heat capacity per mole of a pure substance, and the specific heat capacity, often called simply specific heat, which is the heat capacity per unit mass of a material.

Temperature reflects the average total kinetic energy of particles in matter. Heat is transfer of thermal energy; it flows from regions of high temperature to regions of low temperature. Thermal energy is stored as kinetic energy in the random modes of translation in monatomic substances, and translations and rotations of polyatomic molecules in gases. Additionally, some thermal energy may be stored as the potential energy associated with higher-energy-modes of vibration, whenever they occur in interatomic bonds in any substance. Translation, rotation, and the two types of energy in vibration (kinetic and potential) represent the degrees of freedom of motion which classically contribute to the heat capacity of a thermodynamic system.

For quantum mechanical reasons, some of these degrees of freedom may not be available, or only partially available to store thermal energy, at a given temperature. As the temperature approaches absolute zero, the specific heat capacity of a system also approaches zero, due to loss of available degrees of freedom due to the quantum mechanical effect. Quantum theory can be used to quantitatively predict specific heat capacities in simple systems.


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