Voltaic pile

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A voltaic pile is a set of individual Galvanic cells placed in series. The voltaic pile, invented by Alessandro Volta in 1800, was the first electric battery. Building on Galvani's 1780s discovery of how a circuit of two metals and a frog's leg can cause the frog's leg to respond, Volta demonstrated in 1791 that when two metals and brine-soaked cloth or cardboard are arranged in a circuit they produce an electric current. In 1800, Volta stacked several pairs of alternating copper (or silver) and zinc discs (electrodes) separated by cloth or cardboard soaked in brine (electrolyte) to increase the electrolyte conductivity.[1] When the top and bottom contacts were connected by a wire, an electric current flowed through the voltaic pile and the connecting wire.


Electromotive force

The strength of the pile is expressed in terms of its electromotive force, or emf, given in volts. Volta characterized the emf of a pair of metals in terms of the difference in their voltages, which he could measure. His theory of contact tension considered that the emf, which drives the electric current through a circuit containing a voltaic cell, occurs at the contact between the two metals. Sir Humphry Davy and Andrew Crosse were among the first to develop large voltaic piles.[2]


On March 20, 1800, Volta wrote to the London Royal Society to describe the technique for producing electric current using his pile. On learning of the voltaic pile, William Nicholson and Anthony Carlisle used it to discover the electrolysis of water. Humphry Davy showed that the electromotive force, which drives the electric current through a circuit containing a single voltaic cell, was caused by a chemical reaction, not by the voltage difference between the two metals. He also used the voltaic pile to decompose chemicals and to produce new chemicals. William Hyde Wollaston showed that electricity from voltaic piles had identical effects to those of electricity produced by friction. In 1802 Vasily Petrov used voltaic piles in the discovery and research of electric arc effects.

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