!Modified on November 25, 1996 !added +M efficiency to F reactions. !for CO+F+M=CF:O+M, 3 times faster & +H2O efficiency is 18.0. !also added +M efficiency of CHF3 for both C/H/O and F reactions. !CHF3+H=CF3+H2 Sophia-U's parameters are employed. !CF:O+H=CO+HF Vandooren's rate constant is employed. ! ELEMENTS H O C N F AR END SPECIES N2 AR H2 O2 H2O H2O2 H O OH HO2 CH4 CH3 CH2 CH2* CH C C2H6 C2H5 C2H4 C2H3 C2H2 C2H CH3OH CH3O CH2OH CH2O HCO CO CO2 CH2CO HCCO HCCOH HF F CH2F2 CHF3 CF4 CH2F CHF2 CF3 CHF CF2 CF CF3O CHF:O CF2:O CF:O CHFCO FCCO-E CF2CO CH3-CF3 CF3-CF3 CH3-CHF CH3-CF2 CH2F-CH2 CHF2-CH2 CHF2-CF2 CF3-CH2 CH2:CHF CH2:CF2 CF2:CF2 CH2:CF CHF:CH-Z CF2:CH C2HF END REACTIONS 2O+M<=>O2+M 1.200E+17 -1.000 0.00 H2/2.40/ H2O/15.40/ CH4/2.00/ CO/1.75/ CO2/3.60/ C2H6/3.00/ AR/0.83/ CHF3/2.00/ O+H+M<=>OH+M 5.000E+17 -1.000 0.00 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ O+H2<=>H+OH 5.000E+04 2.670 6290.00 O+HO2<=>OH+O2 2.000E+13 0.000 0.00 O+H2O2<=>OH+HO2 9.630E+06 2.000 4000.00 O+CH<=>H+CO 5.700E+13 0.000 0.00 O+CH2<=>H+HCO 8.000E+13 0.000 0.00 O+CH2*<=>H2+CO 1.500E+13 0.000 0.00 O+CH2*<=>H+HCO 1.500E+13 0.000 0.00 O+CH3<=>H+CH2O 8.430E+13 0.000 0.00 O+CH4<=>OH+CH3 1.020E+09 1.500 8600.00 O+CO+M<=>CO2+M 6.020E+14 0.000 3000.00 H2/2./ O2/6./ H2O/6./ CH4/2./ CO/1.5/ CO2/3.5/ C2H6/3./ AR/0.5/ CHF3/2./ O+HCO<=>OH+CO 3.000E+13 0.000 0.00 O+HCO<=>H+CO2 3.000E+13 0.000 0.00 O+CH2O<=>OH+HCO 3.900E+13 0.000 3540.00 O+CH2OH<=>OH+CH2O 1.000E+13 0.000 0.00 O+CH3O<=>OH+CH2O 1.000E+13 0.000 0.00 O+CH3OH<=>OH+CH2OH 3.880E+05 2.500 3100.00 O+CH3OH<=>OH+CH3O 1.300E+05 2.500 5000.00 O+C2H<=>CH+CO 5.000E+13 0.000 0.00 O+C2H2<=>H+HCCO 1.020E+07 2.000 1900.00 O+C2H2<=>OH+C2H 4.600E+19 -1.410 28950.00 O+C2H2<=>CO+CH2 1.020E+07 2.000 1900.00 O+C2H3<=>H+CH2CO 3.000E+13 0.000 0.00 O+C2H4<=>CH3+HCO 1.920E+07 1.830 220.00 O+C2H5<=>CH3+CH2O 1.320E+14 0.000 0.00 O+C2H6<=>OH+C2H5 8.980E+07 1.920 5690.00 O+HCCO<=>H+2CO 1.000E+14 0.000 0.00 O+CH2CO<=>OH+HCCO 1.000E+13 0.000 8000.00 O+CH2CO<=>CH2+CO2 1.750E+12 0.000 1350.00 O2+CO<=>O+CO2 2.500E+12 0.000 47800.00 O2+CH2O<=>HO2+HCO 1.000E+14 0.000 40000.00 H+O2+M<=>HO2+M 2.800E+18 -0.860 0.00 O2/0.00/ H2O/0.00/ CO/0.75/ CO2/1.50/ C2H6/1.50/ N2/0.00/ AR/0.00/ CHF3/1.00/ H+2O2<=>HO2+O2 3.000E+20 -1.720 0.00 H+O2+H2O<=>HO2+H2O 1.652E+19 -0.760 0.00 H+O2+N2<=>HO2+N2 3.750E+20 -1.720 0.00 H+O2+AR<=>HO2+AR 7.000E+17 -0.800 0.00 H+O2<=>O+OH 8.300E+13 0.000 14413.00 2H+M<=>H2+M 1.000E+18 -1.000 0.00 H2/0.00/ H2O/0.00/ CH4/2.00/ CO2/0.00/ C2H6/3.00/ AR/0.63/ CHF3/2.00/ 2H+H2<=>2H2 9.000E+16 -0.600 0.00 2H+H2O<=>H2+H2O 6.000E+19 -1.250 0.00 2H+CO2<=>H2+CO2 5.500E+20 -2.000 0.00 H+OH+M<=>H2O+M 2.200E+22 -2.000 0.00 H2/0.73/ H2O/3.65/ CH4/2.00/ C2H6/3.00/ AR/0.38/ CHF3/2.00/ H+HO2<=>O+H2O 3.970E+12 0.000 671.00 H+HO2<=>O2+H2 2.800E+13 0.000 1068.00 H+HO2<=>2OH 1.340E+14 0.000 635.00 H+H2O2<=>HO2+H2 1.210E+07 2.000 5200.00 H+H2O2<=>OH+H2O 1.000E+13 0.000 3600.00 H+CH<=>C+H2 1.100E+14 0.000 0.00 H+CH2(+M)<=>CH3(+M) 2.500E+16 -0.800 0.00 LOW / 3.200E+27 -3.140 1230.00/ TROE/ 0.6800 78.00 1995.00 5590.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ H+CH2*<=>CH+H2 3.000E+13 0.000 0.00 H+CH3(+M)<=>CH4(+M) 1.782E+16 -0.630 383.00 LOW / 2.484E+33 -4.760 2440.00/ TROE/ 0.7830 74.00 2941.00 6964.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ H+CH4<=>CH3+H2 6.600E+08 1.620 10840.00 H+HCO(+M)<=>CH2O(+M) 1.090E+12 0.480 -260.00 LOW / 1.350E+24 -2.570 1425.00/ TROE/ 0.7824 271.00 2755.00 6570.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ H+HCO<=>H2+CO 7.340E+13 0.000 0.00 H+CH2O(+M)<=>CH2OH(+M) 5.400E+11 0.454 3600.00 LOW / 1.270E+32 -4.820 6530.00/ TROE/ 0.7187 103.00 1291.00 4160.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ CHF3/2.00/ H+CH2O(+M)<=>CH3O(+M) 5.400E+11 0.454 2600.00 LOW / 2.200E+30 -4.800 5560.00/ TROE/ 0.7580 94.00 1555.00 4200.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ CHF3/2.00/ H+CH2O<=>HCO+H2 2.300E+10 1.050 3275.00 H+CH2OH(+M)<=>CH3OH(+M) 1.800E+13 0.000 0.00 LOW / 3.000E+31 -4.800 3300.00/ TROE/ 0.7679 338.00 1812.00 5081.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ CHF3/2.00/ H+CH2OH<=>H2+CH2O 2.000E+13 0.000 0.00 H+CH2OH<=>OH+CH3 1.200E+13 0.000 0.00 H+CH2OH<=>CH2*+H2O 6.000E+12 0.000 0.00 H+CH3O(+M)<=>CH3OH(+M) 5.000E+13 0.000 0.00 LOW / 8.600E+28 -4.000 3025.00/ TROE/ 0.8902 144.00 2838.00 45569.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ CHF3/2.00/ H+CH3O<=>H+CH2OH 3.400E+06 1.600 0.00 H+CH3O<=>H2+CH2O 2.000E+13 0.000 0.00 H+CH3O<=>OH+CH3 3.200E+13 0.000 0.00 H+CH3O<=>CH2*+H2O 1.600E+13 0.000 0.00 H+CH3OH<=>CH2OH+H2 1.700E+07 2.100 4870.00 H+CH3OH<=>CH3O+H2 4.200E+06 2.100 4870.00 H+C2H(+M)<=>C2H2(+M) 1.000E+17 -1.000 0.00 LOW / 3.750E+33 -4.800 1900.00/ TROE/ 0.6464 132.00 1315.00 5566.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ H+C2H2(+M)<=>C2H3(+M) 5.600E+12 0.000 2400.00 LOW / 3.800E+40 -7.270 7220.00/ TROE/ 0.7507 98.50 1302.00 4167.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ H+C2H3(+M)<=>C2H4(+M) 6.080E+12 0.270 280.00 LOW / 1.400E+30 -3.860 3320.00/ TROE/ 0.7820 207.50 2663.00 6095.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ H+C2H3<=>H2+C2H2 3.000E+13 0.000 0.00 H+C2H4(+M)<=>C2H5(+M) 1.080E+12 0.454 1820.00 LOW / 1.200E+42 -7.620 6970.00/ TROE/ 0.9753 210.00 984.00 4374.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ H+C2H4<=>C2H3+H2 1.325E+06 2.530 12240.00 H+C2H5(+M)<=>C2H6(+M) 5.210E+17 -0.990 1580.00 LOW / 1.990E+41 -7.080 6685.00/ TROE/ 0.8422 125.00 2219.00 6882.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ H+C2H5<=>H2+C2H4 2.000E+12 0.000 0.00 H+C2H6<=>C2H5+H2 1.150E+08 1.900 7530.00 H+HCCO<=>CH2*+CO 1.000E+14 0.000 0.00 H+CH2CO<=>HCCO+H2 5.000E+13 0.000 8000.00 H+CH2CO<=>CH3+CO 1.130E+13 0.000 3428.00 H+HCCOH<=>H+CH2CO 1.000E+13 0.000 0.00 H2+CO(+M)<=>CH2O(+M) 4.300E+07 1.500 79600.00 LOW / 5.070E+27 -3.420 84350.00/ TROE/ 0.9320 197.00 1540.00 10300.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ OH+H2<=>H+H2O 2.160E+08 1.510 3430.00 2OH(+M)<=>H2O2(+M) 7.400E+13 -0.370 0.00 LOW / 2.300E+18 -0.900 -1700.00/ TROE/ 0.7346 94.00 1756.00 5182.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ 2OH<=>O+H2O 3.570E+04 2.400 -2110.00 OH+HO2<=>O2+H2O 4.616E+13 0.000 -500.00 OH+H2O2<=>HO2+H2O 1.750E+12 0.000 320.00 DUPLICATE OH+H2O2<=>HO2+H2O 5.800E+14 0.000 9560.00 DUPLICATE OH+C<=>H+CO 5.000E+13 0.000 0.00 OH+CH<=>H+HCO 3.000E+13 0.000 0.00 OH+CH2<=>H+CH2O 2.000E+13 0.000 0.00 OH+CH2<=>CH+H2O 1.130E+07 2.000 3000.00 OH+CH2*<=>H+CH2O 3.000E+13 0.000 0.00 OH+CH3(+M)<=>CH3OH(+M) 6.300E+13 0.000 0.00 LOW / 2.700E+38 -6.300 3100.00/ TROE/ 0.2105 83.50 5398.00 8370.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ CHF3/2.00/ OH+CH3<=>CH2+H2O 5.600E+07 1.600 5420.00 OH+CH3<=>CH2*+H2O 2.500E+13 0.000 0.00 OH+CH4<=>CH3+H2O 1.000E+08 1.600 3120.00 OH+CO<=>H+CO2 4.760E+07 1.228 70.00 OH+HCO<=>H2O+CO 5.000E+13 0.000 0.00 OH+CH2O<=>HCO+H2O 3.430E+09 1.180 -447.00 OH+CH2OH<=>H2O+CH2O 5.000E+12 0.000 0.00 OH+CH3O<=>H2O+CH2O 5.000E+12 0.000 0.00 OH+CH3OH<=>CH2OH+H2O 1.440E+06 2.000 -840.00 OH+CH3OH<=>CH3O+H2O 6.300E+06 2.000 1500.00 OH+C2H<=>H+HCCO 2.000E+13 0.000 0.00 OH+C2H2<=>H+CH2CO 2.180E-04 4.500 -1000.00 OH+C2H2<=>H+HCCOH 5.040E+05 2.300 13500.00 OH+C2H2<=>C2H+H2O 3.370E+07 2.000 14000.00 OH+C2H2<=>CH3+CO 4.830E-04 4.000 -2000.00 OH+C2H3<=>H2O+C2H2 5.000E+12 0.000 0.00 OH+C2H4<=>C2H3+H2O 3.600E+06 2.000 2500.00 OH+C2H6<=>C2H5+H2O 3.540E+06 2.120 870.00 OH+CH2CO<=>HCCO+H2O 7.500E+12 0.000 2000.00 2HO2<=>O2+H2O2 1.300E+11 0.000 -1630.00 DUPLICATE 2HO2<=>O2+H2O2 4.200E+14 0.000 12000.00 DUPLICATE HO2+CH2<=>OH+CH2O 2.000E+13 0.000 0.00 HO2+CH3<=>O2+CH4 1.000E+12 0.000 0.00 HO2+CH3<=>OH+CH3O 1.333E+13 0.000 0.00 HO2+CO<=>OH+CO2 1.500E+14 0.000 23600.00 HO2+CH2O<=>HCO+H2O2 1.000E+12 0.000 8000.00 C+O2<=>O+CO 5.800E+13 0.000 576.00 C+CH2<=>H+C2H 5.000E+13 0.000 0.00 C+CH3<=>H+C2H2 5.000E+13 0.000 0.00 CH+O2<=>O+HCO 3.300E+13 0.000 0.00 CH+H2<=>H+CH2 1.096E+08 1.790 1670.00 CH+H2O<=>H+CH2O 5.710E+12 0.000 -755.00 CH+CH2<=>H+C2H2 4.000E+13 0.000 0.00 CH+CH3<=>H+C2H3 3.000E+13 0.000 0.00 CH+CH4<=>H+C2H4 6.000E+13 0.000 0.00 CH+CO(+M)<=>HCCO(+M) 5.000E+13 0.000 0.00 LOW / 2.690E+28 -3.740 1936.00/ TROE/ 0.5757 237.00 1652.00 5069.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ CH+CO2<=>HCO+CO 3.400E+12 0.000 690.00 CH+CH2O<=>H+CH2CO 9.460E+13 0.000 -515.00 CH+HCCO<=>CO+C2H2 5.000E+13 0.000 0.00 CH2+O2<=>OH+HCO 1.320E+13 0.000 1500.00 CH2+H2<=>H+CH3 5.000E+05 2.000 7230.00 2CH2<=>H2+C2H2 3.200E+13 0.000 0.00 CH2+CH3<=>H+C2H4 4.000E+13 0.000 0.00 CH2+CH4<=>2CH3 2.460E+06 2.000 8270.00 CH2+CO(+M)<=>CH2CO(+M) 8.100E+11 0.500 4510.00 LOW / 2.690E+33 -5.110 7095.00/ TROE/ 0.5907 275.00 1226.00 5185.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ CH2+HCCO<=>C2H3+CO 3.000E+13 0.000 0.00 CH2*+N2<=>CH2+N2 1.500E+13 0.000 600.00 CH2*+AR<=>CH2+AR 9.000E+12 0.000 600.00 CH2*+O2<=>H+OH+CO 2.800E+13 0.000 0.00 CH2*+O2<=>CO+H2O 1.200E+13 0.000 0.00 CH2*+H2<=>CH3+H 7.000E+13 0.000 0.00 CH2*+H2O(+M)<=>CH3OH(+M) 2.000E+13 0.000 0.00 LOW / 2.700E+38 -6.300 3100.00/ TROE/ 0.1507 134.00 2383.00 7265.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ CHF3/2.00/ CH2*+H2O<=>CH2+H2O 3.000E+13 0.000 0.00 CH2*+CH3<=>H+C2H4 1.200E+13 0.000 -570.00 CH2*+CH4<=>2CH3 1.600E+13 0.000 -570.00 CH2*+CO<=>CH2+CO 9.000E+12 0.000 0.00 CH2*+CO2<=>CH2+CO2 7.000E+12 0.000 0.00 CH2*+CO2<=>CO+CH2O 1.400E+13 0.000 0.00 CH2*+C2H6<=>CH3+C2H5 4.000E+13 0.000 -550.00 CH3+O2<=>O+CH3O 3.083E+13 0.000 28800.00 CH3+O2<=>OH+CH2O 3.600E+10 0.000 8940.00 CH3+H2O2<=>HO2+CH4 2.450E+04 2.470 5180.00 2CH3(+M)<=>C2H6(+M) 2.120E+16 -0.970 620.00 LOW / 1.770E+50 -9.670 6220.00/ TROE/ 0.5325 151.00 1038.00 4970.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ 2CH3<=>H+C2H5 4.990E+12 0.100 10600.00 CH3+HCO<=>CH4+CO 2.648E+13 0.000 0.00 CH3+CH2O<=>HCO+CH4 3.320E+03 2.810 5860.00 CH3+CH3OH<=>CH2OH+CH4 3.000E+07 1.500 9940.00 CH3+CH3OH<=>CH3O+CH4 1.000E+07 1.500 9940.00 CH3+C2H4<=>C2H3+CH4 2.270E+05 2.000 9200.00 CH3+C2H6<=>C2H5+CH4 6.140E+06 1.740 10450.00 HCO+H2O<=>H+CO+H2O 3.366E+18 -1.000 17000.00 HCO+M<=>H+CO+M 1.870E+17 -1.000 17000.00 H2/2.00/ H2O/0.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ CHF3/2.00/ HCO+O2<=>HO2+CO 7.600E+12 0.000 400.00 CH2OH+O2<=>HO2+CH2O 1.800E+13 0.000 900.00 CH3O+O2<=>HO2+CH2O 4.280E-13 7.600 -3530.00 C2H+O2<=>HCO+CO 5.000E+13 0.000 1500.00 C2H+H2<=>H+C2H2 4.070E+05 2.400 200.00 C2H3+O2<=>HCO+CH2O 3.980E+12 0.000 -240.00 C2H4(+M)<=>H2+C2H2(+M) 8.000E+12 0.440 88770.00 LOW / 7.000E+50 -9.310 99860.00/ TROE/ 0.7345 180.00 1035.00 5417.00 / H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ C2H5+O2<=>HO2+C2H4 8.400E+11 0.000 3875.00 HCCO+O2<=>OH+2CO 1.600E+12 0.000 854.00 2HCCO<=>2CO+C2H2 1.000E+13 0.000 0.00 HF + M = H + F + M 3.12E13 0.00 99320. !81BAU/DUX +134 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ H2 + F = H + HF 2.56E12 0.50 650. !db k20 ref fit -31 OH + F = O + HF 2.00E13 0.00 0. !wt1 (H+HNO3) -33 HO2 + F = O2 + HF 2.89E12 0.50 0. !db k20 ref fit -86 H2O + F = OH + HF 1.30E09 1.50 0. !wt k19 ref fit -16 H2O2 + F = HO2 + HF 1.73E12 0.50 0. !db k20 ref fit -48 CH2* + HF = CHF + H2 2.08E07 1.27 8330. !wtk19 -14 CH2F + H = CH2* + HF 8.19E15 -0.63 505. !wtk19 - 8 CH2F + H = CHF + H2 5.21E08 1.16 1000. !wtk19 CHF + HF = CH2F2 3.64E24 -4.26 4060. !wtk19 -71 CF2 + H2 = CH2F2 1.70E06 -0.71 40900. !wtk19 CHF2 + H = CH2F2 2.75E06 -0.32 7690. !wtk19 -102 CHF + HF = CF2 + H2 5.77E06 1.35 17900. !wtk19 CHF2 + H = CHF + HF 1.49E14 -0.11 101. !wtk19 CHF2 + H = CF2 + H2 5.50E03 2.42 -420. !wtk19 CHF3 + M = CF2 + HF + M 2.39E30 -4.00 69050. !db k20 ref fit +61 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ CF3 + H = CF2 + HF 5.50E13 0.00 0. !93nist17 298 -46 CF3 + F = CF4 1.60E38 -7.90 8950. !wtk22 ref CH3 + F = CH2* + HF 1.62E16 -0.88 -981. !93nist17 -17 CH2F + F = CHF + HF 5.00E13 0.00 0. !93nist17 -46 CHF2 + F = CF2 + HF 3.00E13 0.00 0. !wtsang4 -68 CH3 + F = CH2F + H 1.36E12 -0.39 -265. !93nist17 - 9 CH2F2 + H = CHF2 + H2 1.65E03 3.00 5600. !dbk19fitexpt - 6 CHF3 + H = CF3 + H2 3.76E13 0.00 13145. !refine Sophia-U'96 CH2F2 + H = CH2F + HF 5.50E13 0.00 34100. !93nist17 -16 CHF3 + H = CHF2 + HF 8.00E13 0.00 40300. !93nist17 - 4 CF4 + H = CF3 + HF 1.10E15 0.00 44600. !71KOC/MOI chk - 4 CH2F2 + O = CHF2 + OH 2.25E07 1.50 6100. !db k19 ref fit CHF3 + O = CF3 + OH 1.00E08 1.50 9250. !db k20 ref fit CH2F2 + OH = CHF2 + H2O 2.80E07 1.70 2540. !91COH/WES OK3 -10 CHF3 + OH = CF3 + H2O 5.77E06 1.80 4292. !87COH/BEN OK3 -10 CHF2 + H2O2 = CH2F2 + HO2 1.20E10 0.00 -600. !dbk19ref -12 CF3 + H2O2 = CHF3 + HO2 1.20E10 0.00 -600. !dbk19ref -21 CH2F2 + CH3 = CHF2 + CH4 8.70E10 0.00 10200. !65PRI/BRY chk - 2 CH2F2 + C2H5 = CHF2 + C2H6 9.00E10 0.00 14600. !dbk19refE*1.43 + 2 CH2F2 + C2H3 = CHF2 + C2H4 9.00E10 0.00 9200. !dbk19refE*0.90 - 6 CF3 + CH4 = CHF3 + CH3 8.34E11 0.00 10920. !78ART/BEL - 4 CF3 + C2H6 = CHF3 + C2H5 7.59E11 0.00 7980. !78ART/BEL -10 CF3 + C2H4 = CHF3 + C2H3 8.00E11 0.00 12000. !dbk19refE*1.1 - 2 CH2F2 + CF3 = CHF2 + CHF3 7.20E11 0.00 11200. !67GIL/QUI chk - 8 CH2O + CHF2 = HCO + CH2F2 5.54E03 2.81 7800. !dbk19refE*1.3 -10 CH2O + CF3 = HCO + CHF3 5.54E03 2.81 4600. !dbk19refE*.79 -19 CH3OH + CHF2 = CH3O + CH2F2 1.44E01 3.10 9000. !dbk19ref E*1.3 + 4 CH3OH + CF3 = CH3O + CHF3 1.44E01 3.10 5500. !dbk19ref E*.79 - 4 CH3OH + CHF2 = CH2OH + CH2F2 3.20E01 3.20 9300. !dbk19refE*1.3 - 5 CH3OH + CF3 = CH2OH + CHF3 3.20E01 3.20 5700. !dbk19refE*.79 -13 HCO + CHF2 = CO + CH2F2 0.90E14 0.00 0. !nistk19 ref HCO + CF3 = CO + CHF3 0.90E14 0.00 0. !nistk19 ref -91 HCO + CH2F = CH2CO + HF 2.70E13 0.00 0. !est, k19 HCO + CHF2 = CHFCO + HF 2.70E13 0.00 0. !est, k19 HCO + CF3 = CF2CO + HF 2.70E13 0.00 0. !est, k19 CH2F + O2 => CHF:O + O + H 2.26E09 1.14 28500. !db k22 ref+dH CHF2 + O2 => CF2:O + O + H 2.26E09 1.14 16500. !db k22 ref+dH CF3 + O2 = CF3O + O 2.26E09 1.14 21500. !wt k19 CH2F + O = CHF:O + H 5.70E13 0.00 0. !k19 -90 CHF2 + O = CF2:O + H 3.70E13 0.00 0. !k19 -103 CF3 + O = CF2:O + F 1.90E13 0.00 0. !k19 293K -80 CH2F + OH = CH2O + HF 2.50E13 0.00 0. !wt k19 ref -95 CHF2 + OH = CHF:O + HF 2.50E13 0.00 0. !wt k19 ref -105 CF3 + OH = CF2:O + HF 2.00E13 0.00 0. !wt k19 ref -114 CH2F + HO2 =>CHF:O + OH + H 1.50E13 0.00 0. !wt k19 ref CHF2 + HO2 =>CF2:O + OH + H 1.50E13 0.00 0. !wt k19 ref CF3 + HO2 = CF3O + OH 1.00E13 0.00 0. !wt k19 ref CHF2 + HO2 = CH2F2 + O2 3.00E12 0.00 0. !wt k19 ref -50 CF3 + HO2 = CHF3 + O2 2.00E12 0.00 0. !wt k15 ref -58 CF3O + M = CF2:O + F + M 9.03E26 -3.42 21700. !wt k19 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ CF3O + H = CF2:O + HF 1.00E14 0.00 0. !nistk19 CF3O + H2 => CF2:O+HF + H 1.00E13 0.00 5000. !k22 TEST CF3O + H2O => CF2:O+HF + OH 1.00E13 0.00 5000. !k22 TEST CF3O + CH4 => CF2:O+HF + CH3 8.00E12 0.00 2300. !k22 TEST CF3O + C2H6 => CF2:O+HF + C2H5 1.20E13 0.00 2300. !k22 TEST CF3O + C2H4 => CF2:O+HF + C2H3 1.00E13 0.00 5000. !k22 TEST CF3O + C2H2 => CF2:O + CH2:CF 1.00E13 0.00 5000. !k22 TEST CF3O + CH2O => CF2:O+HF + HCO 5.00E12 0.00 5000. !k22 TEST CF3O + HCO => CF2:O+HF + CO 5.00E12 0.00 2000. !k22 TEST CHF + O2 = CHF:O + O 2.00E13 0.00 16500. !db k19 E-10 -60 CF2 + O2 = CF2:O + O 2.00E13 0.00 26500. !77KEA/MAT -50 CHF + O = CO + HF 9.00E13 0.00 0. !db k19 298K -181 CF2 + O = CF:O + F 7.00E13 0.00 1000. !k23 reffit -169 CF + F = CF2 6.00E13 0.00 0. !db k19 295K CHF + OH = HCO + HF 4.00E12 0.00 0. !k24 ref/5 -94 CF2 + OH = CF:O + HF 4.00E12 0.00 3500. !k24 ref/5 -71 CHF + OH = CHF:O + H 2.00E13 0.00 0. !k24 CF2 -77 CF2 + OH = CF2:O + H 2.00E13 0.00 3500. !k24 reffit -68 CHF + HO2 = CHF:O + OH 1.00E13 0.00 0. !k24 CF2 + HO2 = CF2:O + OH 1.00E13 0.00 3500. !k24 CHF + HO2 = CH2F + O2 2.00E12 0.00 0. !k24 CF2 + HO2 = CHF2 + O2 2.00E12 0.00 3500. !k24 CHF + H2O = CH2O + HF 5.00E12 0.00 6500. !k23 -64 CF2 + H2O = CHF:O + HF 5.00E12 0.00 25000. !k23 -53 CHF + H = CH + HF 2.95E14 0.00 0. !k23 ref CF2 + H = CF + HF 2.00E14 0.00 1250. !k23 reffit CH2O + CHF = HCO + CH2F 1.00E13 0.00 15000. !k23 refCH4 CH2O + CHF = CH2CO + HF 1.00E13 0.00 15000. !k23 refCH4 CH2O + CF2 = HCO + CHF2 1.00E13 0.00 41000. !k23 refCH4 +22 CH2O + CF2 = CHFCO + HF 1.00E13 0.00 41000. !k23 refCH4 HCO + CHF = CO + CH2F 2.00E13 0.00 15000. !k23 refCH4 HCO + CF2 = CO + CHF2 2.00E13 0.00 41000. !k23 refCH4 CH + HF = CF + H2 3.00E13 0.00 0. !nist k19 -17 CF + O2 = CF:O + O 2.00E13 0.00 1800. !dbk22fit pee/van CF + H2O = CHF:O + H 2.00E13 0.00 17000. !dbk22 ref Cl CF + H =>CH + F 4.00E13 0.00 750. !k22dbfitref CF + O = CO + F 4.00E13 0.00 1000. !dbk22fitref CF + OH = CO + HF 3.00E13 0.00 1000. !k23 ref O CF + HO2 =>CF:O + OH 3.00E13 0.00 0. !nist k19 test CF + CH3 =>CH2:CF + H 3.00E13 0.00 0. !nist k19 test CF + C2H5 =>CH2:CF + CH3 3.00E13 0.00 0. !nist k19 test CF + C2H3 =>C2HF + CH2 3.00E13 0.00 0. !nist k19 test CF + CH2 =>C2HF + H 3.00E13 0.00 0. !nist k19 test CF + CH2* =>C2HF + H 3.00E13 0.00 0. !nist k19 test CF + CH4 =>CH2:CHF + H 5.00E12 0.00 10000. !dbk23guess CF + C2H4 =>C2H2 + CH2F 1.00E13 0.00 0. !nist k19 test CF + CH2O =>CHF + HCO 1.00E13 0.00 8000. !db k19 test + 7 CF + HCO =>CHF + CO 1.00E13 0.00 0. !db k19 test CHF:O + M = CO + HF + M 2.48E25 -3.00 43000. !db k20 ref fit H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ CF:O + F = CF2:O 1.00E12 0.00 0. !wtsang1 -131 CF2:O + H2O =>CO2 + HF + HF 7.40E-3 3.84 25100. !k22 bacrrkm CHF:O + H = CF:O + H2 1.10E08 1.77 3000. !prw ref/2 - 4 CF2:O + H = CF:O + HF 2.40E07 1.88 35900. !k22 abstract DUP CF2:O + H = CF:O + HF 1.20E10 0.83 22300. !k22 th/CHF2O DUP CF2:O + H = CF:O + HF 5.50E08 1.42 18900. !k22 th/CF2OH DUP CHF:O + O = CF:O + OH 9.00E12 0.00 3080. !prw ref/2 - 2 CHF:O + OH = CF:O + H2O 1.72E09 1.18 -447. !prw ref/2 -18 CF2:O + OH =>CO2 + F + HF 2.70E03 2.38 21000. !k23 bac/rrkm CF:O + H2O2 = CHF:O + HO2 1.00E11 0.00 3900. !dbk19refE*0.56 -13 CHF:O + CH3 = CF:O + CH4 2.00E12 0.00 9000. !dbk19refuplim - 5 CHF:O + CHF2 = CF:O + CH2F2 2.00E12 0.00 9000. !db k19 ref 0 CHF:O + CF3 = CF:O + CHF3 2.00E12 0.00 9000. !db k19 ref - 8 CHF:O + C2H3 = CF:O + C2H4 2.00E12 0.00 5000. !dbk19refE*0.9 CHF:O + C2H5 = CF:O + C2H6 2.00E12 0.00 13000. !dbk19refE*1.43 CO + F + M = CF:O + M 3.09E19 -1.40 -487. !refined *3 H2/2.00/ H2O/18.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ CF:O + O2 =>CO2 + F + O 2.00E13 0.00 24000. !nist k20 +24 CF:O + H = CO + HF 2.50E13 0.00 0. !refine Vandooren94 CF:O + O = CO2 + F 3.00E13 0.00 0. !wt k19 ref CF:O + OH = CO2 + HF 3.00E13 0.00 0. !nist k19 CF:O + HO2 =>CO2 + F + OH 3.00E13 0.00 0. !wt k19 ref CF:O + CH3 = CH2CO + HF 2.70E13 0.00 0. !est, k19 CF:O + CH2F = CHFCO + HF 2.70E13 0.00 0. !est, k19 CF:O + CHF2 = CF2CO + HF 2.70E13 0.00 0. !est, k19 CF:O + CF:O = CO + CF2:O 2.23E13 0.00 318. !92MAR/SZE2 CH3-CF3 = CH2:CF2 + HF 1.00E14 0.00 68700. !71TSC/QUI OK3 CH2F-CH2 + H = C2H4 + HF 1.44E20 -2.12 1730. !wt k19 CH3-CHF + H = C2H4 + HF 2.27E20 -2.21 1950. !wt k19 CHF2-CH2 + H = CH2:CHF + HF 5.24E16 -0.933 880. !wt k19 CH3-CF2 + H = CH2:CHF + HF 2.09E16 -0.854 848. !wt k19 CF3-CH2 + H = CH2:CF2 + HF 1.12E21 -2.27 2240. !wt k19 CH2F-CH2 + H = CH3 + CH2F 3.80E11 0.635 633. !wt k19 CH3-CHF + H = CH3 + CH2F 3.47E10 0.90 1370. !wt k19 CHF2-CH2 + H = CH3 + CHF2 2.02E06 2.16 451. !k19 CH3-CF2 + H = CH3 + CHF2 1.62E05 2.50 1370. !wt k19 CF3-CH2 + H = CH3 + CF3 2.48E11 0.816 2870. !wt k19 CHF2-CF2 + H = CHF2 + CHF2 3.25E15 -0.524 3000. !wt k19 CF3-CH2 + H = CH3-CF3 7.27E42 -9.86 7360. !wt k19 CH3 + CH2F = C2H4 + HF 2.35E19 -1.86 1870. !wt k19 CH2F + CH2F = CH2:CHF + HF 7.56E21 -2.79 2590. !wt k19 CH3 + CHF2 = CH2:CHF + HF 1.90E15 -0.586 634. !wt k19 CH2F + CHF2 = CH2:CF2 + HF 2.23E20 -2.41 2910. !wt k19 CH3 + CF3 = CH2:CF2 + HF 5.53E19 -1.94 2440. !wt k19 CHF2 + CF3 = CF2:CF2 + HF 7.00E16 -1.17 4330. !wt k19 CH3 + CF3 = CH3-CF3 1.78E33 -6.64 5020. !wt k19 CF3 + CF3 = CF3-CF3 1.63E36 -7.26 7050. !wt k19 CH2F-CH2 + H = CH3-CHF + H 1.87E01 3.10 137. !wt k19 CHF2-CH2 + H = CH3-CF2 + H 1.59E-3 4.35 157. !wt k19 CH2F2+ CH2* = CH2:CHF + HF 2.00E13 0.00 0. !k22 ref CHF3 + CH2* = CH2:CF2 + HF 1.00E13 0.00 0. !k22 ref CH4 + CHF = C2H4 + HF 4.00E13 0.00 15000. !k22 BAC-MP4 CH2F2 + CHF = CH2:CF2 + HF 1.00E13 0.00 15000. !k22 refCH4 CF4 + CHF = CF2:CF2 + HF 4.00E13 0.00 31000. !k22 refCH2 CH4 + CF2 = CH2:CHF + HF 4.00E13 0.00 41000. !k22 BAC-MP4 CHF3 + CF2 = CF2:CF2 + HF 1.00E13 0.00 41000. !k22 refCH4 CF4 + CF2 =>CF3-CF3 4.00E13 0.00 51000. !k23 refCH4 CH3 + CH2F = CH4 + CHF 3.00E13 0.00 3400. !k22 bac CHF2 + CH2F = CH2F2 + CHF 3.00E13 0.00 4400. !k22 ref CF3 + CH2F = CHF3 + CHF 3.00E13 0.00 4600. !k22 ref CH3 + CHF2 = CH4 + CF2 3.00E13 0.00 800. !k22 67BRY/PRI CHF2 + CHF2 = CH2F2 + CF2 3.00E13 0.00 1600. !k22 84PRI/NIL CF3 + CHF2 = CHF3 + CF2 3.00E13 0.00 2000. !k22 69PRI/FOL CH3-CF3 + H = CF3-CH2 + H2 4.00E10 1.10 12700. !dbk17refA*10E+8+ 3 CH3-CF3 + O = CF3-CH2 + OH 2.00E10 1.10 9700. !dbk17refA*5E+5 + 4 CH3-CF3 + OH = CF3-CH2 + H2O 4.08E09 1.10 4670. !87COH/BEN OK3 -12 CF3-CH2 + H2O2 = CH3-CF3 + HO2 9.00E09 0.00 1000. !db k19 ref CH3-CF3 + CH3 = CF3-CH2 + CH4 2.00E11 0.00 12000. !wtsang2 + 2 CH3-CF3 + C2H3 = CF3-CH2 + C2H4 2.00E11 0.00 9000. !wtsang CH3 -3 + 5 CH3-CF3 + C2H5 = CF3-CH2 + C2H6 2.00E11 0.00 15000. !wtsang CH3 +3 + 7 CH3-CF3 + CHF2 = CF3-CH2 + CH2F2 2.00E11 0.00 12000. !db k16 CH3 CH3-CF3 + CF3 = CF3-CH2 + CHF3 1.45E12 0.00 13500. !67GIL/QUI chk CH3-CHF + O2 = CH2:CHF + HO2 2.56E19 -2.77 1977. !prw6 ref CH3-CF2 + O2 = CH2:CF2 + HO2 2.56E19 -2.77 1977. !prw6 ref CH2F-CH2 + O2 = CH2:CHF + HO2 2.56E19 -2.77 1977. !prw6 ref CHF2-CH2 + O2 = CH2:CF2 + HO2 2.56E19 -2.77 1977. !prw6 ref CHF2-CF2 + O2 = CF2:CF2 + HO2 2.56E19 -2.77 1977. !prw6 ref CF3-CH2 + O2 =>CF3 + CH2O + O 1.30E13 0.00 44000. !nistk19 CF3+dH CH2F-CH2 + O = CH2CO+HF + H 6.60E13 0. 0. !k24 CHF2-CH2 + O = CHFCO+HF + H 6.60E13 0. 0. !k24 CF3-CH2 + O = CF2CO+HF + H 6.60E13 0. 0. !k24 CH3-CHF + O = CH2CO+HF + H 4.40E13 0. 0. !k24 CH3-CF2 + O = CH2CO+HF + F 2.20E13 0. 0. !k24 CHF2-CF2 + O = CF2CO+HF + F 2.20E13 0. 0. !k24 CH2F-CH2 + O = CH2O + CH2F 3.30E13 0. 0. !k24 CHF2-CH2 + O = CH2O + CHF2 3.30E13 0. 0. !k24 CF3-CH2 + O = CH2O + CF3 3.30E13 0. 0. !k24 CH3-CHF + O = CHF:O + CH3 2.20E13 0. 0. !k24 CH3-CF2 + O = CF2:O + CH3 1.10E13 0. 0. !k24 CHF2-CF2 + O = CF2:O + CHF2 1.10E13 0. 0. !k24 CH2F-CH2 + OH =>CH2CO+HF + H2 6.60E13 0. 0. !k24 CHF2-CH2 + OH =>CHFCO+HF + H2 6.60E13 0. 0. !k24 CF3-CH2 + OH =>CF2CO+HF + H2 6.60E13 0. 0. !k24 CH3-CHF + OH =>CH2CO+H2 + HF 4.40E13 0. 0. !k24 CH3-CF2 + OH =>CH2CO+HF + HF 2.20E13 0. 0. !k24 CHF2-CF2 + OH =>CF2CO+HF + HF 2.20E13 0. 0. !k24 CH2F-CH2 + OH = CH2:CHF + H2O 6.60E13 0. 1510. !k24 CHF2-CH2 + OH = CH2:CF2 + H2O 4.40E13 0. 1510. !k24 CH3-CHF + OH = CH2:CHF + H2O 6.60E13 0. 1510. !k24 CH3-CF2 + OH = CH2:CF2 + H2O 6.60E13 0. 1510. !k24 CHF2-CF2 + OH = CF2:CF2 + H2O 2.20E13 0. 1510. !k24 CH2F-CH2 + CH3 = CH2:CHF + CH4 1.30E13 -0.5 0. !k24 r C2H5 CHF2-CH2 + CH3 = CH2:CF2 + CH4 6.50E12 -0.5 0. !k24 CH3-CHF + CH3 = CH2:CHF + CH4 1.95E13 -0.5 0. !k24 CH3-CF2 + CH3 = CH2:CF2 + CH4 1.95E13 -0.5 0. !k24 CHF2-CF2 + CH3 = CF2:CF2 + CH4 6.50E12 -0.5 0. !k24 CH3-CHF + HO2 =>CH3+CHF:O+ OH 3.00E13 0. 0. !wt k19 ref CH3-CF2 + HO2 =>CH3+CF2:O+ OH 3.00E13 0. 0. !wt k19 ref CH2F-CH2 + HO2 =>CH2F+CH2O+ OH 3.00E13 0. 0. !wt k19 ref CHF2-CH2 + HO2 =>CHF2+CH2O+ OH 3.00E13 0. 0. !wt k19 ref CHF2-CF2 + HO2 =>CHF2+CF2:O+OH 3.00E13 0. 0. !wt k19 ref CF3-CH2 + HO2 =>CF3 +CH2O+ OH 3.00E13 0. 0. !wt k19 ref CH3-CHF + HO2 = CH2:CHF + H2O2 3.00E11 0. 0. !wt k19 ref CH3-CF2 + HO2 = CH2:CF2 + H2O2 3.00E11 0. 0. !wt k19 ref CH2F-CH2 + HO2 = CH2:CHF + H2O2 2.00E11 0. 0. !wt k19 ref CHF2-CH2 + HO2 = CH2:CF2 + H2O2 1.00E11 0. 0. !wt k19 ref CHF2-CF2 + HO2 = CF2:CF2 + H2O2 1.00E11 0. 0. !wt k19 ref CF3-CH2 + HO2 = CH3-CF3 + O2 3.00E11 0. 0. !wt k19 ref CF3-CH2 + CH2O = CH3-CF3 + HCO 5.50E03 2.80 5900. !nistk19 ref CH2:CHF = C2H2 + HF 1.00E14 0.00 70800. !TSCJPC74,992,70 20 CH2:CF2 = C2HF + HF 2.50E14 0.00 86000. !TSCJPC74,4075,70 45 CH2* + CHF = C2H2 + HF 17.02E19 -2.12 2380. !db k19 ref CH2* + CF2 = C2HF + HF 17.02E19 -2.12 2380. !db k19 ref CHF + CHF = C2HF + HF 17.02E19 -2.12 2380. !db k19 ref CH2* + CHF = CH2:CHF 3.10E24 -3.80 2830. !db k19 ref CH2* + CF2 = CH2:CF2 3.10E24 -3.80 2830. !db k19 ref CH2* + CHF = CH2:CF + H 1.64E07 1.56 5740. !db k19 ref CH2* + CHF = CHF:CH-Z + H 1.64E07 1.56 5740. !db k19 ref CH2* + CF2 = CF2:CH + H 3.28E07 1.56 5740. !db k19 ref CH2:CF + H = C2H2 + HF 5.98E20 -2.31 1940. !db k19 ref CHF:CH-Z + H = C2H2 + HF 5.98E20 -2.31 1940. !db k19 ref CF2:CH + H = C2HF + HF 5.98E20 -2.31 1940. !db k19 ref CH2:CF + H = CH2:CHF 2.40E34 -7.11 5040. !db k19 ref CHF:CH-Z + H = CH2:CHF 2.40E34 -7.11 5040. !db k19 ref CF2:CH + H = CH2:CF2 2.40E34 -7.11 5040. !db k19 ref CF2:CF2 + M = CF2 + CF2 + M 3.96E50 -9.06 85300. !k23 xk 78SCH/WAG H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/ CHF3/2.00/ CH2:CHF + H(+M)= CH2F-CH2 (+M) 4.20E08 1.5 990. !prw6 ref LOW/3.19E27 -2.8 -54./ !prw6 ref H2/2.0/ CO/2.0/ CO2/3.0/ H2O/5.0/ CHF3/2.00/ !prw6 ref CH2:CHF + H(+M)= CH3-CHF (+M) 4.20E08 1.5 990. !prw6 ref LOW/3.19E27 -2.8 -54./ !prw6 ref H2/2.0/ CO/2.0/ CO2/3.0/ H2O/5.0/ CHF3/2.00/ !prw6 ref CH2:CF2 + H(+M)= CHF2-CH2 (+M) 4.20E08 1.5 990. !prw6 ref LOW/3.19E27 -2.8 -54./ !prw6 ref H2/2.0/ CO/2.0/ CO2/3.0/ H2O/5.0/ CHF3/2.00/ !prw6 ref CH2:CF2 + H(+M)= CH3-CF2 (+M) 4.20E08 1.5 990. !prw6 ref LOW/3.19E27 -2.8 -54./ !prw6 ref H2/2.0/ CO/2.0/ CO2/3.0/ H2O/5.0/ CHF3/2.00/ !prw6 ref CF2:CF2 + H(+M)= CHF2-CF2 (+M) 8.40E08 1.5 990. !prw6 ref LOW/6.37E27 -2.8 -54./ !prw6 ref H2/2.0/ CO/2.0/ CO2/3.0/ H2O/5.0/ CHF3/2.00/ !prw6 ref CH2:CHF + H = CHF:CH-Z + H2 0.33E06 2.53 12241. !prw6 ref CH2:CHF + H = CH2:CF + H2 0.33E06 2.53 12241. !prw6 ref CH2:CF2 + H = CF2:CH + H2 0.67E06 2.53 12241. !prw6 ref C2H4 + F = CH2:CHF + H 2.00E13 0.00 0. !wt k19 ref CH2:CHF + F = CH2:CF2 + H 2.00E12 0.00 0. !wt k19 ref CH2:CHF + O = CH2F + HCO 5.30E09 1.00 1310. !k19 fit CVE CH2:CF2 + O = CHF2 + HCO 4.30E09 1.00 1490. !k19 fit CVE CF2:CF2 + O = CF2 + CF2:O 1.90E09 1.00 0. !k19 fit CVE CH2:CHF + O = CH3 + CF:O 5.30E09 1.00 2300. !k19 ref+1 CH2:CHF + OH = CHF:CH-Z + H2O 2.00E06 2.00 2850. !k19 ref - 6 CH2:CHF + OH = CH2:CF + H2O 1.00E06 2.00 2850. !k19 ref -10 CH2:CF2 + OH = CF2:CH + H2O 2.00E06 2.00 2850. !k19 ref - 3 CH2:CF + O2 = CH2O + CF:O 4.48E26 -4.55 5480. !92WES direct DUP CHF:CH-Z + O2 = CHF:O + HCO 4.48E26 -4.55 5480. !92WES direct DUP CF2:CH + O2 = CF2:O + HCO 4.48E26 -4.55 5480. !92WES direct DUP CH2:CF + O2 = CH2O + CF:O 1.05E38 -8.22 7030. !92WES k(a/s) DUP CHF:CH-Z + O2 = CHF:O + HCO 1.05E38 -8.22 7030. !92WES k(a/s) DUP CF2:CH + O2 = CF2:O + HCO 1.05E38 -8.22 7030. !92WES k(a/s) DUP CH2:CF + O = CH2CO + F 3.00E13 0.00 0. !prw6 ref CHF:CH-Z + O = CHFCO + H 3.00E13 0.00 0. !prw6 ref CF2:CH + O = CF2CO + H 3.00E13 0.00 0. !prw6 ref CH2:CF + OH = CH2CO + HF 3.00E13 0.00 0. !k19 ref CHF:CH-Z + OH = CH2CO + HF 3.00E13 0.00 0. !k19 ref CH2:CF + OH = CH3 + CF:O 3.00E13 0.00 0. !k19 ref CHF:CH-Z + OH = CH2F + HCO 3.00E13 0.00 0. !k19 ref C2HF +H (+M)= CH2:CF (+M) 2.80E12 0.00 2410. !prw6 ref LOW/1.33E27 -3.5 2410./ H2/2./ CO/2./ CO2/3./ H2O/5./ CHF3/2.00/ C2HF +H (+M)= CHF:CH-Z (+M) 1.40E12 0.00 2410. !prw6 ref LOW/0.67E27 -3.5 2410./ H2/2./ CO/2./ CO2/3./ H2O/5./ CHF3/2.00/ C2HF + O = FCCO-E + H 1.00E07 2.00 1900. !MB A077 *2Ch, /2C's C2HF + OH = CHFCO + H 2.18E-4 4.50 -1000. !ref MB A089 C2HF + OH = CH2F + CO 2.50E-4 4.00 -2000. !ref/2, MB A090 C2HF + OH = HCCO + HF 2.50E-4 4.00 -2000. !ref/2, MB A090 CH2F + CH2 = CH2:CHF + H 4.00E13 0.00 0. !prw k17 CH3 CH2F + CH2 = C2H4 + F 4.00E13 0.00 0. !prw k17 CH3 CHF2 + CH2 = CH2:CF2 + H 4.00E13 0.00 0. !prw k17 CH3 CHF2 + CH2 = CH2:CHF + F 4.00E13 0.00 0. !prw k17 CH3 CF3 + CH2 = CH2:CF2 + F 4.00E13 0.00 0. !db k19 prw ref CH2F + CH2* = CH2:CHF + H 4.00E12 0.00 0. !prw k17 CH3 CH2F + CH2* = C2H4 + F 2.00E12 0.00 0. !prw k17 CH3 CHF2 + CH2* = CH2:CF2 + H 2.00E12 0.00 0. !prw k17 CH3 CHF2 + CH2* = CH2:CHF + F 4.00E12 0.00 0. !prw k17 CH3 CF3 + CH2* = CH2:CF2 + F 6.00E12 0.00 0. !prw k17 CH3 CH3 + CHF = CH2:CHF + H 6.00E12 0.00 0. !k24 rCH2S -46 CH2F + CHF = CH2:CHF + F 2.00E12 0.00 0. !k24 -37 CH3 + CF2 = CH2:CF2 + H 6.00E12 0.00 3500. !k24 -21 CH2F + CF2 = CH2:CF2 + F 2.00E12 0.00 3500. !k24 -12 CHF2 + CF2 = CF2:CF2 + H 2.00E12 0.00 3500. !k24 - 6 CHFCO + H = CH2F + CO 1.13E13 0.00 3428. !ref MB A094 CF2CO + H = CHF2 + CO 1.13E13 0.00 3428. !ref MB A094 CHFCO + H = FCCO-E + H2 5.00E13 0.00 8000. !ref MB A095 CHFCO + O = CHF:O + CO 1.00E13 0.00 8000. !est k19 CF2CO + O = CF2:O + CO 1.00E13 0.00 8000. !est k19 CHFCO + OH = FCCO-E + H2O 7.50E12 0.00 2000. !ref MB A097 HCCO + F = CHF + CO 3.00E13 0.00 0. !ref MB A101 FCCO-E + F = CF2 + CO 3.00E13 0.00 0. !ref MB A101 FCCO-E + H = CHF + CO 1.00E14 0.00 0. !ref MB A101 FCCO-E + O = CF:O + CO 1.00E14 0.00 0. !ref MB A102 CH4 + F = CH3 + HF 5.90E12 0.50 450. !dbk19fit -31 CH2F2 + F = CHF2 + HF 9.00E13 0.00 1850. !dbk19 300K fit -35 CHF3 + F = CF3 + HF 4.50E13 0.00 3700. !dbk19 300K fit -27 CH3OH + F = CH3O + HF 2.62E09 1.44 -205. !91GLA/KOS CH3OH + F = CH2OH + HF 4.62E07 1.97 -300. !91GLA/KOS CH2O + F = HCO + HF 6.00E13 0.00 2000. !db k15 298K -45 CHF:O + F = CF:O + HF 2.65E13 0.00 1800. !90FRA/ZHA OK3 -35 CH3O + F = CH2O + HF 3.00E13 0.00 0. !nistk19 -114 HCO + F = CO + HF 1.00E13 0.00 0. !wtsang1 -120 C2H6 + F = C2H5 + HF 8.00E12 0.00 300. !60FET/KNO2 OK3 -36 CH3-CF3 + F = CF3-CH2 + HF 1.00E14 0.00 4000. !wtsang2 C2H4 + F = C2H3 + HF 1.00E14 0.00 2000. !k23 refch4 -34 CF2:CF2 + F = CF3 + CF2 3.00E13 0.00 0. !k19 ref 298K -18 C2H3 + F = C2H2 + HF 2.00E13 0.00 0. !nist k19 END