Enantioselective Linchpin Catalysis by SOMO Catalysis: An Approach to the Asymmetric a-Chlorination of Aldehydes and Terminal Epoxide Formation
M. Amatore, T. D. Beeson, S. P. Brown, D. W. C. MacMillan
Angew. Chem. Int. Ed., 48, Early View (2009)
Cycle-Specific Organocascade Catalysis: Application to Olefin Hydroamination,
Hydro-oxidation, and Amino-oxidation, and to Natural Product Synthesis
B. Simmons, A. Walji, D. W. C. MacMillan
Angew. Chem. Int. Ed., 48, 4349-4353 (2009)
A process for the rapid removal of dialkylamino-substituents from aromatic rings.
Application to the expedient synthesis of (R)-tolterodine
N. Paras, B. Simmons, D. W. C. MacMillan
Tetrahedron, 6, 3232-3238 (2009)
Enantioselective Organo-SOMO Catalysis: The Carbo-oxidation of Styrenes
T. H. Graham, C. M. Jones, N. T. Jui, D. W. C. MacMillan
J. Am. Chem. Soc., 130, 16494-16495 (2008)
The Advent and Development of Organocatalysis
D. W. C. MacMillan
Nature 455, 304-308 (2008)
Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes
D. Nicewicz, D. W. C. MacMillan
Science, 322, 77-80 (2008)
Total Synthesis and Structural Revision of Callipeltoside C
J. Carpenter, A. B. Northrup, d. M. Chung, J. J. M. Wiener, S.-G. Kim, D. W. C. MacMillan
Angew. Chem. Int. Ed., 47, 3568-3572 (2008)
Enantioselective Organo-SOMO Catalysis: The a-Vinylation of Aldehydes
H. Kim, D. W. C. MacMillan
J. Am. Chem. Soc., 130, 398-399 (2008)
Enantioselective Organocatalytic Transfer Hydrogenation Reactions using Hantzsch Esters
S. G. Ouellet, A. Walji, D. W. C. MacMillan
Acc. Chem. Res., 40, 1327-1339 (2007) **Special issue on hydrogenation & transfer hydrogenation
Organocatalytic Vinyl and Friedel-Crafts Alkylations with Trifluoroborate Salts
S. Lee, D. W. C. MacMillan
J. Am. Chem. Soc., 129, 15438-15439 (2007)
Strategies to Bypass the Taxol Problem: Enantioselective Cascade Catalysis,
A New Approach for the Efficient Construction of Molecular Complexity
A. Walji, D. W. C. MacMillan
Syn. Lett., 10, 1477-1489 (2007)
Enantioselective Organocatalytic Singly Occupied Molecular Orbital Activation: The Enantioselective a-Enolation of Aldehydes
H. Jang, J. Hong, D. W. C. MacMillan
J. Am. Chem. Soc., 129, 7004-7005 (2007)
Enantioselective Organocatalysis Using SOMO Activation
T. D. Beeson, A. Mastracchio, J. Hong, K. Ashton, D. W. C. MacMillan
Science, 316, 582-585 (2007)
Organocatalytic Transfer Hydrogenation of Cyclic Enones
J. B. Tuttle, S. G. Ouellet, D. W. C. MacMillan
J. Am. Chem. Soc., 128, 12662-12663 (2006)
Enantioselective Organocatalytic Epoxidation Using Hypervalent Iodine Reagents
S. Lee, D. W. C. MacMillan
Tetrahedron, 62, 11413-11424 (2006)
Enantioselective Organocatalytic Amine Conjugate Addition
Y. K. Chen, M. Yoshida, D. W. C. MacMillan
J. Am. Chem. Soc., 128, 9328-9329 (2006)
Modern Strategies in Organic Catalysis: The Advent and Development of Iminium Activation
G. Lelais, D. W. C. MacMillan
Aldrichimica Acta, 39, 79-87 (2006)
Enantioselective Organocatalytic Reductive Amination
R. I. Storer, D. E. Carrera, Y. Ni, D. W. C. MacMillan
J. Am. Chem. Soc., 128, 84-86 (2006)
Enantioselective Organo-Cascade Catalysis
Y. Huang, A. M. Walji, C. H. Larsen, D. W. C. MacMillan
J. Am. Chem. Soc., 127, 15051-15053 (2005)
Enantioselective Organocatalytic Intramolecular Diels-Alder Reaction. The Asymmetric Synthesis of Solanapyrone D
R. M. Wilson, W. S. Jen, D. W. C. MacMillan
J. Am. Chem. Soc., 127, 11616-11617 (2005)
Enantioselective Organocatalytic Direct a-Fluorination
T. D. Beeson, D. W. C. MacMillan
J. Am. Chem. Soc., 127, 8826-8828 (2005)
Total Synthesis of Brasoside and Littoralisone
I. K. Mangion, D. W. C. MacMillan
J. Am. Chem. Soc., 127, 3696-3697 (2005)
Enantioselective Organocatalytic Cyclopropanations. The Identification of a New Class of Iminium Catalyst Based Upon Directed Electrostatic Activations
R. K. Kunz, D. W. C. MacMillan
J. Am. Chem. Soc., 127, 3240-3241 (2005)
Enantioselective Organocatalytic Hydride Reduction
S. G. Ouellet, J. B. Tuttle, D. W. C. MacMillan
J. Am. Chem. Soc., 127, 32-33 (2005)
Importance of Iminium Geometry Control in Enamine Catalysis: Identification of a New Catalyst Architecture for Aldehyde-Aldehyde Couplings
I. K. Mangion, A. B. Northrup, D. W. C. MacMillan
Angew. Chem. Int. Ed., 43, 6722-6724 (2004)
Two Step Synthesis of Carbohydrates by Selective Aldol Reactions
A. B. Northrup, D. W. C. MacMillan
Science, 305, 1752-1755 (2004)
Enantioselective Organocatalytic Aldehyde-Aldehyde Cross-Aldol Couplings. The Broad Utility of a-Thioacetal Aldehydes (Special Edition to honor Prof. D. Seebach)
R. I. Storer, D. W. C. MacMillan
Tetrahedron, 60, 7705-7714 (2004)
Enantioselective Organocatalytic Construction of Pyrroloindolines by a Cascade Addition-Cyclization Strategy: Synthesis of (-)-flustramine B (Issue Cover)
J. F. Austin, S. G. Kim, C. J. Sinz, W. J. Xiao, D. W. C. MacMillan
Proc. Nat. Acad. Sci. USA, 101, 5482-8487 (2004)
Enantioselective Organocatalytic Direct Aldol Reaction of a-Oxyladehydes: Step One in a Two-Step Synthesis of Carbohydrates
A. B. Northrup, I. K. Mangion, F. Hettche, D. W. C. MacMillan
Angew. Chem. Int. Ed., 43, 2152-2154 (2004)
The Direct and Enantioselective Organocatalytic a-Chlorination of Aldehydes
M. P. Brochu, S. P. Brown, D. W. C. MacMillan
J. Am. Chem. Soc., 126, 4108-4109 (2004)
The Direct and Enantioselective Organocatalytic a-Oxidation of Aldehydes
S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan
J. Am. Chem. Soc., 125, 10808-10809 (2003)
The First Suzuki Cross-Coupling of Aryltrimethylammonium Ions
S. B. Blakey, D. W. C. MacMillan
J. Am. Chem. Soc., 125, 6046-6047 (2003)
The First Enantioselective Organocatalytic Mukaiyama-Michael Reaction: A Direct Method for the Synthesis of Enantioenriched g-Butenolide Architecture
S. P. Brown, N. C. Goodwin, D. W. C. MacMillan
J. Am. Chem. Soc., 125, 1192-1194 (2003)
Development of a New Lewis Acid-Catalyzed [3,3]-Sigmatropic Rearrangement:
The Allenoate-Claisen Rearrangement
T. H. Lambert, D. W. C. MacMillan
J. Am. Chem. Soc., 124, 13646-13647 (2002)
The Enantioselective Organocatalytic 1,4-Addition of Electron Rich Benzenes to a,b-Unsaturated Aldehydes
N. A. Paras, D. W. C. MacMillan
J. Am. Chem. Soc., 124, 7894-7895 (2002)
The First Direct and Enantioselective Cross-Aldol Reactions of Aldehydes
A. B. Northrup, D. W. C. MacMillan
J. Am. Chem. Soc., 124, 6798-6799 (2002)
The First General Enantioselective Catalytic Diels-Alder Reaction with Simple a,B-Unsaturated Ketones
A. B. Northrup, D. W. C. MacMillan
J. Am. Chem. Soc., 124, 2458-2460 (2002)
Enantioselective Indole Alkylations. Design of a New and Highly Effective Chiral Amine for Iminuim Catalysis
J. F. Austin, D. W. C. MacMillan
J. Am. Chem. Soc., 124, 1172-1173 (2002)
New Strategies in Organocatalysis: The First Enantioselective Organocatalytic Friedel-Crafts Alkylation
N. A. Paras, D. W. C. MacMillan
J. Am. Chem. Soc., 123, 4370-4371 (2001)
Enantioselective Claisen Rearrangements: Development of a First Generation Asymmetric Acyl-Claisen Rearrangement
T. P. Yoon, D. W. C. MacMillan
J. Am. Chem. Soc., 123, 2911-2912 (2001)
Design of a New Cascade Reaction for the Construction of Complex Acyclic Structure: The Tandem Acyl-Claisen Rearrangement
V. M. Dong, D. W. C. MacMillan
J. Am. Chem. Soc., 123, 2448-2449 (2001)
New Strategies for Organic Synthesis: The First Enantioselective Organocatalytic 1,3-Dipolar Cycloaddition
W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan
J. Am. Chem. Soc., 121, 9874-9875 (2000)
New Strategies for Organic Synthesis: The First Highly Enantioselective Organocatalytic Diels-Alder Reaction
K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan
J. Am. Chem. Soc., 122, 4243-4244 (2000)
Development of a New Lewis Acid-Catalyzed Claisen Rearrangement
T. P. Yoon, V. M. Dong, D. W. C. MacMillan
J. Am. Chem. Soc., 122, 9726-9727 (2000)
