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Diffusion

Oxide Growth and Corrosion

· At a surface, a reaction with oxygen will produce a surface oxide layer. Most technical materials that can react with oxygen will have a native oxide layer on their surface.
· The growth of an oxide layer on silicon is an essential process in the fabrication of microelectronic devices. Oxidation of other technical materials by ambient oxygen is an important corrosion mechanism that limits their utility.
· Oxide growth is a diffusion controlled process with either the oxygen or the material diffusing through the growing oxide. The control of this process is essential, and the oxidation mechanism involves a steady state process controlled by the diffusion flux through the oxide overlayer.
· Oxidation is a Fick's first law problem.