Summer Picnic and Recognition of 50 & 60-Year Members
Thursday, June 18, 2009
our guest speaker will be
Dr. Bob Rodgers,
Research Solutions and Resources LLC
"An Introduction to Electrochemical
Impedance Spectroscopy"
The lecture is at 6:00 PM in Bowen Auditorium,
Picnic is at Carl Fields Center immediately following lecture
Princeton University Map
Driving Directions
ABSTRACT
Electrochemistry deals with the interaction of
electrons with molecules, and with reactions associated with the
reactants or products of that interaction. One of the electrical
variables, voltage (E), or current (I), is controlled and the other
is measured.
Electrochemical Impedance Spectroscopy (EIS) is a small
perturbation, nominally nondestructive technique that measures the
relationship between E and I as a function of the frequency of the
perturbation. By analogy with Ohm’s Law (E = I R), the ac components
of E and I are related by E = I Z. The impedance (Z), unlike simple
resistance, depends upon frequency. Impedance is easily measured for
the frequency range from 1 MHz to 10 μHz, so that processes with
characteristic times from microseconds to days can be studied.
EIS began its rise to popularity in the mid-sixties/early seventies.
The advent of computer-controlled instrumentation allowed the
experiment to become routine and rapid. Today, EIS is being used to
study corrosion; to evaluate paint and coating protection; to study
fuel cell chemistry and to monitor cell status; to measure
lubrication oil quality; and as a detection scheme for sensors.
Biography
Dr. Bob Rodgers received undergraduate training at The Polytechnic
Institute of NYU (then Brooklyn Polytechnic Institute) and his PhD
in Analytical Chemistry from Clarkson University. After a post-doc
at Cal Tech he spent seven years teaching at Michigan State
University and Lehigh University. Bob spent the next twenty-nine
years working for manufacturers of commercial electrochemical
instrumentation, first at Princeton Applied Research (PAR) and later
at Gamry Instruments.
Over the course of over forty years, Bob has
been active in the areas of Analytical Voltammetry, Electrochemical
Impedance Spectroscopy (EIS), Corrosion, and general
Electrochemistry. He pioneered the first commercial Electrochemical
Impedance Spectroscopy software while at PAR, and was active in
specifying four generations of that successful product. He is the
author of twenty scientific articles in the areas of
electrochemistry and instrumentation.