PUBLICATIONS


1. Pascal, R. A., Jr., S. Jungk, and G. E. Risinger, Reactions of 2-Dichloromethylbenzimidazole with Certain Primary Amines, J. Heterocyclic Chem. 1978, 15, 141-144.

2. Schroepfer, G. J., Jr., R. A. Pascal, Jr., R. Shaw, and A. A. Kandutsch, Inhibition of Sterol Biosynthesis by 14a-Hydroxymethyl Sterols, Biochem. Biophys. Res. Commun. 1978, 83, 1024-1031.

3. Schroepfer, G. J., Jr., R. A. Pascal, Jr., and A. A. Kandutsch, Inhibition of Sterol Synthesis in Animal Cells by 15-Oxygenated Sterols with the Unnatural cis-C-D Ring Junction: 5a,14b-Cholest-7-en-15a-ol-3-one and 5a,14b-Cholest-7-en-15b-ol-3-one, Biochem. Pharm. 1979, 28, 249-252.

4. Pascal, R. A., Jr., R. Shaw, and G. J. Schroepfer, Jr., Chemical Synthesis of Three 14a-Hydroxymethyl Cholestenols, J. Lipid Res. 1979, 20, 570-578.

5. Pascal, R. A., Jr., C. L. Farris, and G. J. Schroepfer, Jr., Sterol Synthesis: Medium-Pressure Chromatography of C27 Sterol Precursors of Cholesterol on Alumina-Silver Nitrate Columns, Anal. Biochem. 1980, 101, 15-22.

6. Pascal, R. A., Jr., and G. J. Schroepfer, Jr., Sterol Synthesis: Chemical Synthesis of 5a-Cholest-7-en-3b,14a-diol, J. Lipid Res. 1980, 21, 118-122.

7. Pascal, R. A., Jr., and G. J. Schroepfer, Jr., 15-Oxygenated Sterols with the Unnatural cis-C-D Ring Junction: Studies of the Metabolism of 5a,14b-Cholest-7-ene-3b,15a-diol and 5a,14b-Cholest-7-ene-3b,15b-diol, J. Biol. Chem. 1980, 255, 3565-3570.

8. Pascal, R. A., Jr., and G. J. Schroepfer, Jr., Enzymatic Isomerization of the Nuclear Double Bond of 14a-Alkyl Substituted Sterol Precursors of Cholesterol, Biochem. Biophys. Res. Commun. 1980, 94, 932-939.

9. Schroepfer, G. J. Jr., R. A. Pascal, Jr., and A. A. Kandutsch, Inhibition of Sterol Biosynthesis by 14a-Hydroxy-D7-sterols, Experientia 1980, 36, 518.

10. Schroepfer, G. J., Jr., E. J. Parish, R. A. Pascal, Jr., and A. A. Kandutsch, Inhibition of Sterol Biosynthesis in Animal Cells by 14a-Hydroxymethyl Sterols, J. Lipid Res. 1980, 21, 571-584.

11. Pascal, R. A. Jr., P. Chang, and G. J. Schroepfer, Jr., Possible Mechanisms of Demethylation of 14a-Hydroxymethyl Sterols in Cholesterol Biosynthesis, J. Am. Chem. Soc. 1980, 102, 6599-6601.

12. Taylor, U. F., A. Kisic, R. A. Pascal, Jr., A. Izumi, M. Tsuda, and G. J. Schroepfer, A Simple Method for the Isolation of Zymosterol (5a-Cholesta-8,24-dien-3b- ol) from Yeast and Spectral Properties of Zymosterol, J. Lipid Res. 1981, 22, 171-177.

13. Miller, L. R., R. A. Pascal, Jr., and G. J. Schroepfer, Jr., Inhibitors of Sterol Synthesis: Differential Effects of 14a-Hydroxymethyl-5a-cholest-7-ene-3b,15a-diol and 14a-Hydroxymethyl-5a-cholest-6-ene-3b,15a-diol on Sterol Synthesis in Cell-Free Homogenates of Rat Liver, J. Biol. Chem. 1981, 256, 8085-8091.

14. Walsh, C., R. A. Pascal, Jr., M. Johnston, R. Raines, D. Dikshit, A. Krantz, and M. Honma, Mechanistic Studies on the Pyridoxal Phosphate Enzyme 1-Aminocyclopropane-1-carboxylate Deaminase from Pseudomonas sp., Biochemistry 1981, 20, 7509-7519.

15. Pascal, R. A. Jr., N. L. Trang, A. Cerami, and C. Walsh, Purification and Properties of Dihydroorotate Oxidase from Crithidia fasciculata and Trypanosoma brucei, Biochemistry 1983, 22, 171-178.

16. Pascal, R. A., Jr., and C. Walsh, Mechanistic Studies with Deuterated Dihydroorotates on the Dihydroorotate Oxidase from Crithidia fasciculata, Biochemistry 1984, 23, 2745-2752.

17. Pascal, R. A., Jr., M. W. Baum, C. K. Wagner, and L. R. Rodgers, Measurement of Deuterium Kinetic Isotope Effects in Organic Reactions by Natural Abundance Deuterium NMR Spectroscopy, J. Am. Chem. Soc. 1984, 106, 5377-5378.

18. Pascal, R. A., Jr., and Y.-C. J. Chen, Synthesis of 2,6-Dihalo-DL-tyrosines, J. Org. Chem. 1985, 50, 408-410.

19. Pascal, R. A., Jr., M. A. Oliver, and Y.-C. J. Chen, Alternate Substrates and Inhibitors of Bacterial 4-Hydroxyphenylpyruvate Dioxygenase, Biochemistry 1985, 24, 3158-3165.

20. Benecky, M. J., R. A. Copeland, T. R. Hays, E. Lobenstine, R. P. Rava, R. A. Pascal, Jr., and T. G. Spiro, Resonance Raman Spectroscopy of Pyridoxal Schiff Bases, J. Biol. Chem. 1985, 260, 11663-11670.

21. Pascal, R. A., Jr., and D. L. Ziering, Synthesis of Heteroatom-Substituted Analogues of Stearic Acid, J. Lipid Res. 1986, 27, 221-224.

22. Pascal, R. A., Jr., and D.-S. Huang, Reactions of 3-Ethylcatechol and 3-(Methylthio)catechol with Catechol Dioxygenases, Arch. Biochem. Biophys. 1986, 248, 130-137.

23. Pascal, R. A., Jr., J. Spergel, and D. Van Engen, Synthesis and X-Ray Crystallographic Characterization of a (1,3,5)Cyclophane with Three Amide N-H Groups Surrounding a Central Cavity: A Neutral Host for Anion Complexation, Tetrahedron Lett. 1986, 27, 4099-4102.

24. Pascal, R. A., Jr., W. D. McMillan, and D. Van Engen, 9,18-Diphenyl- tetrabenz[a,c,h,j]anthracene: A Remarkably Twisted Polycyclic Aromatic Hydrocarbon, J. Am. Chem. Soc. 1986, 108, 5652-5653.

25. Pascal, R. A., Jr., S. J. Mannarelli, and D. L. Ziering, 10-Thiastearic Acid Inhibits Both Dihydrosterculic Acid Biosynthesis and Growth of the Protozoan Crithidia fasciculata, J. Biol. Chem. 1986, 261, 12441-12443.

26. Pascal, R. A., Jr., M. W. Baum, C. K. Wagner, L. R. Rodgers, and D.-S. Huang, Measurement of Deuterium Kinetic Isotope Effects in Organic and Biochemical Reactions by Natural Abundance Deuterium NMR Spectroscopy, J. Am. Chem. Soc. 1986, 108, 6477-6482.

27. Pascal, R. A., Jr., and D. Van Engen, The Solid State Structure of 9,11,20,22-Tetraphenyltetrabenzo[a,c,l,n]pentacene-10,21-dione: A Longitudinally Twisted Molecular Ribbon, Tetrahedron Lett. 1987, 28, 293-294.

28. Pascal, R. A., Jr., and D.-S. Huang, Mechanism-Based Inactivation of Catechol 2,3-Dioxygenase by 3-[(Methylthio)methyl]catechol, J. Am. Chem. Soc. 1987, 109, 2854-2855.

29. Pascal, R. A., Jr., W. D. McMillan, D. Van Engen, and R. G. Eason, Synthesis and Structure of Longitudinally Twisted Polycyclic Aromatic Hydrocarbons, J. Am. Chem. Soc. 1987, 109, 4660-4665.

30. Pascal, R. A., Jr., and R. B. Grossman, Comment on the Structure and Proton NMR Spectrum of 2,8,17-Trithia[4(5,12)][9]metacyclophane, J. Org. Chem. 1987, 52, 4616.

31. Pascal, R. A., Jr., R. B. Grossman, and D. Van Engen, Synthesis of in-[3(4,10)][7]Metacyclophane: Projection of an Aliphatic Hydrogen Toward the Center of an Aromatic Ring, J. Am. Chem. Soc. 1987, 109, 6878-6880.

32. Pascal, R. A., Jr., D. Van Engen, B. Kahr, and W. D. McMillan, Twisted Polycyclic Aromatic Hydrocarbons: Structural Studies of Protic and Deuterated 1,2,3,4-Tetraphenyltriphenylenes, J. Org. Chem. 1988, 53, 1687-1689.

33. Rahman, M. D., D. L. Ziering, S. J. Mannarelli, K. L. Swartz, D.-S. Huang, and R. A. Pascal, Jr., Effects of Sulfur-Containing Analogs of Stearic Acid on Growth and Fatty Acid Biosynthesis in the Protozoan Crithidia fasciculata, J. Med. Chem. 1988, 31, 1656-1659.

34. Rahman, M. D., H. M. Seidel, and R. A. Pascal, Jr., Synthesis of 24-Heteroatom-Substituted Cholestanols, J. Lipid Res. 1988, 29, 1543-1548.

35. Pascal, R. A., Jr., C. G. Winans, and D. Van Engen, Small, Strained Cyclophanes with Methine Hydrogens Projected toward the Centers of Aromatic Rings, J. Am. Chem. Soc. 1989, 111, 3007-3010.

36. Beach, D. H., R. A. Pascal, Jr., and G. G. Holz, Jr., Effects of Thiastearic Acids on Growth and on Dihydrosterculic Acid and Other Phospholipid Fatty Acyl Groups of Leishmania Promastigotes, Mol. Biochem. Parasitol. 1989, 35, 57-66.

37. West, A. P., Jr., D. Van Engen, and R. A. Pascal, Jr., Short Synthesis and Structure of a Large Molecular Bowl, J. Am. Chem. Soc. 1989, 111, 6846-6847.

38. Ziering, D. L., and R. A. Pascal, Jr., Mechanism-Based Inhibition of Bacterial gamma-Butyrobetaine Hydroxylase, J. Am. Chem. Soc. 1990, 112, 834-838.

39. Smyth, N., D. Van Engen, and R. A. Pascal, Jr., Synthesis of Longitudinally Twisted Polycyclic Aromatic Hydrocarbons via a Highly Substituted Aryne, J. Org. Chem. 1990, 55, 1937-1940.

40. Rahman, M. D., and R. A. Pascal, Jr., Inhibitors of Ergosterol Biosynthesis and Growth of the Trypanosomatid Protozoan Crithidia fasciculata, J. Biol. Chem. 1990, 265, 4989-4996.

41. Han, H., and R. A. Pascal, Jr., alpha-Ketoisocaproate Dioxygenase: The Stereochemical Course of the Hydroxylation Reaction, J. Org. Chem. 1990, 55, 5173-5176.

42. Pascal, R. A., Jr., A. P. West, Jr., and D. Van Engen, Synthesis and Structure of an in-Phosphaphane: Enforced Interaction of a Phosphine and an Aromatic Ring, J. Am. Chem. Soc. 1990, 112, 6406-6407.

43. Bill, T. J., S. Chen, R. A. Pascal, Jr., and J. Schwartz, "Outer Sphere" Oxidation of Non-Conjugated Dienes by Simple Iron(III) Complexes: A New Mechanistic Consideration for Oxidation of Arachidonic Acid by Lipoxygenase, J. Am. Chem. Soc. 1990, 112, 9019-9020.

44. L'Esperance, R. P., D. Van Engen, R. Dayal, and R. A. Pascal, Jr., A Study of Substituent Effects on Hydrogen-to-Arene Nonbonded Interactions, J. Org. Chem. 1991, 56, 688-694.

45. L'Esperance, R. P., A. P. West, Jr., D. Van Engen, and R. A. Pascal, Jr., In-Cyclophanes Containing Second-Row Elements Poised Above Aromatic Rings, J. Am. Chem. Soc. 1991, 113, 2672-2676.

46. Pascal, R. A., Jr., and S. Mischke, The beta-Secondary Deuterium Kinetic Isotope Effect for the Insertion of Dichlorocarbene into a C-H Bond, J. Org. Chem. 1991, 56, 6954-6957.

47. Van Engen, D., M. D. Rahman, A. Yun, and R. A. Pascal, Jr., The Structures of 3beta-Tetrahydropyranyloxy-5alpha-cholesta-20(21),24-diene and 3beta-Tetrahydropyranyloxy-21-nor-5alpha-ergost-24-en-20-one, Acta Crystallogr. Sect. C 1991, C47, 2591-2594.

48. Pascal, R. A., Jr., and D. M. Ho, Synthesis and Structure of 1,7-Dichlorodibenzo[ef,kl]heptalene-4,10-dione, a Saddle-Shaped Polycyclic Aromatic Compound, Tetrahedron Lett. 1992, 33, 13-16.

49. West, A. P., Jr., D. Van Engen, and R. A. Pascal, Jr., Attempted Synthesis of a 1,2,3,4-Tetraphenylfluoreno[1,9-gh]quinoline, J. Org. Chem. 1992, 57, 784-786.

50. Pascal, R. A., Jr., and D. M. Ho, Nitrogen-Chlorine Donor-Acceptor Interactions Dominate the Structure of Crystalline Cyanuric Chloride, Tetrahedron Lett. 1992, 33, 4707-4708.

51. Pascal, R. A., Jr., Tormented Aromatic Compounds, Pure Appl. Chem. 1993, 65, 105-110.

52. Li, R., S. Ganguli, and R. A. Pascal, Jr., Synthesis of Sulfur-Substituted Phosphatidylethanolamines and Inhibition of Protozoan Cyclopropane Fatty Acid Synthase, Tetrahedron Lett. 1993, 34, 1279-1282.

53. Li, R., and R. A. Pascal, Jr., Sulfur-Substituted Phosphatidylethanolamines, J. Org. Chem. 1993, 58, 1952-1954.

54. West, A. P., Jr., N. Smyth, C. M. Kraml, D. M. Ho, and R. A. Pascal, Jr., Synthesis, Molecular Structure, and Properties of In-Phosphaphanes with Substituted Basal Aromatic Rings, J. Org. Chem. 1993, 58, 3502-3506.

55. Ho, D. M., and R. A. Pascal, Jr., Decacyclene: A Molecular Propeller with Helical Crystals, Chem. Mater. 1993, 5, 1358-1361.

56. Pascal, R. A., Jr., and D. M. Ho, Molecular Structure of Rebek's Diacid- Quinoxaline: Confirmation of Two-Point Binding, J. Am. Chem. Soc. 1993, 115, 8507-8508.

57. Ho, D. M., and R. A. Pascal, Jr., Structure of a Cyclophane Containing a 1,5,2,4,6,8-Dithiatetrazocine Ring, Acta Crystallogr., Sect. C 1994, C50, 108-110.

58. Xu, K., D. M. Ho, and R. A. Pascal, Jr., Azaaromatic Chlorides: A Prescription for Crystal Structures with Extensive Nitrogen-Chlorine Donor-Acceptor Interactions, J. Am. Chem. Soc. 1994, 116, 105-110.

59. Mathai, M. S., and R. A. Pascal, Jr., Synthesis of New C-19-Functionalized Cholesterols, Steroids 1994, 59, 244-247.

60. Pascal, R. A., Jr., and R. P. L'Esperance, Conformational Dynamics of the Bent 1,5,2,4,6,8-Dithiatetrazocines, J. Am. Chem. Soc. 1994, 116, 5167-5171.

61. Pascal, R. A., Jr., and D. M. Ho, Molecular Structures of Host-Guest Complexes with Rebek's Diacid, Tetrahedron 1994, 50, 8559-8568.

62. Shibata, K., A. A. Kulkarni, D. M. Ho, and R. A. Pascal, Jr., Perchlorotriphenylene, J. Am. Chem. Soc. 1994, 116, 5983-5984.

63. Shibata, K., A. A. Kulkarni, D. M. Ho, and R. A. Pascal, Jr., The Pursuit of Perchlorotriphenylene, J. Org. Chem. 1995, 60, 428-434.

64. Xu, K., D. M. Ho, and R. A. Pascal, Jr., Molecular Association Mediated by Nitrogen-Chlorine Donor-Acceptor Interactions, J. Org. Chem. 1995, 60, 7186-7191.

65. Qiao, X., M. A. Padula, D. M. Ho, N. J. Vogelaar, C. E. Schutt, and R. A. Pascal, Jr., Octaphenylnaphthalene and Decaphenylanthracene, J. Am. Chem. Soc. 1996, 118, 741-745.

66. Dell, S., D. M. Ho, and R. A. Pascal, Jr., Cyclophanes with Sharp Corners: Synthesis of Macrocycles Containing One or Two 1,5,2,4,6,8-Dithiatetrazocine Rings, Inorg. Chem. 1996, 35, 2866-2871.

67. Qiao, X., D. M. Ho, and R. A. Pascal, Jr., The Carbazole Connection: Unusual Products from the Diazotization of Anthranilic Acids, J. Org. Chem. 1996, 61, 6748-6750.

68. Pascal, R. A., Jr., M. L. Carter, M. R. Johnson, and D. M. Ho, A Cyclophane Bridged by an Inwardly Pyramidalized Olefin, Tetrahedron Lett. 1996, 37, 8125-8128.

69. Tong, L., D. M. Ho, N. J. Vogelaar, C. E. Schutt, and R. A. Pascal, Jr., Albatrossidine: A Large, Easily Synthesized Molecular Cleft, Tetrahedron Lett. 1997, 38, 7-10.

70. Qiao, X., D. M. Ho, and R. A. Pascal, Jr., An Extraordinarily Twisted Polycyclic Aromatic Hydrocarbon, Angewandte Chemie Int. Ed. English 1997, 36, 1531-1532.

71. Tong, L., D. M. Ho, N. J. Vogelaar, C. E. Schutt, and R. A. Pascal, Jr., The Albatrossenes: Large, Cleft-Containing, Polyphenyl Polycyclic Aromatic Hydrocarbons, J. Am. Chem. Soc. 1997, 119, 7291-7302.

72. Qiao, X., I. Pelczer, and R. A. Pascal, Jr., Synthesis and Stereochemistry of Ortho-Methylated Octaphenylnaphthalenes, Chirality 1998, 10, 154-158.

73. Debad, J. D., S. K. Lee, X. Qiao, R. A. Pascal, Jr., and A. J. Bard, Electrogenerated Chemiluminescence 60. Spectroscopic Properties and Electrogenerated Chemiluminescence of Decaphenylanthracene and Octaphenylnaphthalene, Acta Chem. Scand. 1998, 52, 45-50.

74. Gildersleeve, J., R. A. Pascal, Jr., and D. Kahne, Sulfenate Intermediates in the Sulfoxide Glycosylation Reaction, J. Am. Chem. Soc. 1998, 120, 5961-5969.

75. Tong, L., H. Lau, D. M. Ho, and R. A. Pascal, Jr., Polyphenylbiphenyls and Polyphenylfluorenes, J. Am. Chem. Soc. 1998, 120, 6000-6006.

76. Dell, S., N. J. Vogelaar, D. M. Ho, and R. A. Pascal, Jr., An In-Fluorosilaphane: The Largest In-Functionality Is a Uniquely Encapsulated Fluorine Atom, J. Am. Chem. Soc. 1998, 120, 6421-6422.

77. Barnett, L., D. M. Ho, K. K. Baldridge, and R. A. Pascal, Jr., The Structure of Hexabenzotriphenylene and the Problem of Overcrowded "D3h" Polycyclic Aromatic Compounds, J. Am. Chem. Soc. 1999, 121, 727-733.

78. Pan, W., D. M. Ho, R. A. Pascal, Jr., and M. Jones, Jr., Reaction of Dicarbethoxy-carbene with 1,3-Cyclooctadiene. Entry to the trans-Bicyclo[6.1.0]non-cis-2-ene System, Tetrahedron Lett. 1999, 40, 3089-3092.

79. Zhang, J., D. M. Ho, and R. A. Pascal, Jr., Curious Reduction Products from a Strained Polycyclic Quinone, Tetrahedron Lett. 1999, 40, 3859-3862.

80. Dell, S., D. M. Ho, and R. A. Pascal, Jr., In- and Out-Cyclophanes Bearing Nonhydrogen Bridgehead Substituents, J. Org. Chem. 1999, 64, 5626-5633.

81. Hennessy, M. H., Z. G. Soos, R. A. Pascal, Jr., and A. Girlando, Vibronic Structure of PTCDA Stacks: The Exciton-Phonon-Charge-Transfer Dimer, Chemical Physics 1999, 245, 199-212.

82. Hennessy, M. H., R. A. Pascal, Jr., and Z. G. Soos, Vibronic Model of PTCDA Stacks: Fluorescence and Relaxation Energies, Proceedings of SPIE 1999, 3937, 89-100.

83. Chen, Y. T., K. K. Baldridge, D. M. Ho, and R. A. Pascal, Jr., Interconversion and Reactions of In- and Out-Isomers of a Triarylphosphine-Containing Cyclophane, J. Am. Chem. Soc. 1999, 121, 12082-12087.

84. Hayashi, N., D. M. Ho, and R. A. Pascal, Jr., An Unusual Cobalt-Mediated Cleavage of a Hindered Alkyne, Tetrahedron Lett. 2000, 41, 4261-4264.

85. Watson, J. A., Jr., R. A. Pascal, Jr., D. M. Ho, and K. V. Kilway, Synthesis and Structure of a Twisted, Colossal Quinone, Tetrahedron Lett. 2000, 41, 5005-5008.

86. Hill, I. G., A. Kahn, Z. G. Soos, and R. A. Pascal, Jr., Charge-Separation Energy in Films of pi-Conjugated Organic Molecules, Chem. Phys. Lett. 2000, 327, 181-188.

87. Pascal, R. A., Jr., L. Barnett, X. Qiao, and D. M. Ho, Giant Cyclophanes Built from Polyphenyl Aromatic Substructures, J. Org. Chem. 2000, 65, 7711-7717.

88. Hennessy, M. H., R. A. Pascal, Jr., and Z. G. Soos, Vibronic Structure of Frenkel and Charge-Transfer Excitons in PTCDA, Mol. Cryst. Liq. Cryst 2001, 355, 41-64.

89. Pascal, R. A., Jr., N. Hayashi, and D. M. Ho, Conformational Subtlety in Large Polyphenylene Molecules, Tetrahedron 2001, 57, 3549-3555.

90. Specht, K. M., J. Nam, D. M. Ho, N. Berova, R. K. Kondru, D. N. Beratan, P. Wipf, R. A. Pascal, Jr., and D. Kahne, Determining Absolute Configuration in Flexible Molecules: A Case Study, J. Am. Chem. Soc. 2001, 123, 8961-8966.

91. Soos, Z. G., E. V. Tsiper, and R. A. Pascal, Jr., Charge Redistribution and Electronic Polarization in Organic Molecular Crystals, Chem. Phys. Lett. 2001, 652-658.

92. Pascal, R. A., Jr., A Concise Set of "Large", Symmetric Molecules for Evaluation of Modern Computational Methods, J. Phys. Chem. A 2001, 105, 9040-9048.

93. Zhang, J., D. M. Ho, and R. A. Pascal, Jr., Synthesis of an Extremely Crowded Naphthalene via a Stable Norbornadienone, J. Am. Chem. Soc. 2001, 123, 10919-10926.

94. Pascal, R. A., Jr., M. S. Mathai, X. Shen, and D. M. Ho, Trimerization of a Steroid Ketone to Form a Chiral Molecular Cleft, Angew. Chem. Int. Ed. 2001, 40, 4746-4748.

95. Dias, J. R., R. A. Pascal, Jr., J. Morrill, A. J. Holder, H. Gao, and C. Barnes, Remarkable Structures of Cyclotri(deoxycholate) and Cyclotetra(24-norcholate) Acetate Esters, J. Am. Chem. Soc. 2002, 124, 4647-4652.

96. Lu, J., J. Zhang, X. Shen, D. M. Ho, and R. A. Pascal, Jr., Octaphenylbiphenylene and Dodecaphenyltriptycene, J. Am. Chem. Soc. 2002, 124, 8035-8041.

97. Schuster, I. I., L. Craciun, D. M. Ho, and R. A. Pascal, Jr., Synthesis of a Strained, Air-Sensitive, Polycyclic Aromatic Hydrocarbon by Means of a New 1,4-Benzadiyne Equivalent, Tetrahedron 2002, 58, 8875-8882.

98. Shen, X., D. M. Ho, and R. A. Pascal, Jr., Synthesis and Structure of a Polyphenylene Macrocycle Related to "Cubic Graphite", Org. Lett. 2003, 5, 369-371.

99. Semmelhack, M. F., L. Wu, R. A. Pascal, Jr., and D. M. Ho, Conformational Control in Activation of an Enediyne, J. Am. Chem. Soc. 2003, 125, 10496-10497.

100. Kilway, K. V., K. A. Lindgren, J. W. Vincent, J. A. Watson, Jr., R. G. Clevenger, R. D. Ingalls, D. M. Ho, and R. A. Pascal, Jr., Unexpected Conversion of a Polycyclic Thiophene to a Macrocyclic Anhydride, Tetrahedron 2004, 60, 2433-2438.

101. Shen, X. F., D. M. Ho, and R. A. Pascal, Jr., Synthesis of Polyphenylene Dendrimers Related to "Cubic Graphite", J. Am. Chem. Soc. 2004, 126, 5798-5805.

102. Craciun, L., D. M. Ho, Maitland Jones, Jr., and R. A. Pascal, Jr., A Carboranylpentaphenylbenzene, Tetrahedron Lett. 2004, 45, 4985-4987.

103. Pascal, R. A., Jr., Molecular "Iron Maidens": Ultrashort Nonbonded Contacts in Cyclophanes and Other Molecules, Eur. J. Org. Chem. 2004, 3763-3771.

104. Lu, J., D. M. Ho, N. J. Vogelaar, C. M. Kraml, and R. A. Pascal, Jr., A Pentacene with a 144 Twist, J. Am. Chem. Soc. 2004, 126, 11168-11169.

105. Lowry, M. S., W. R. Hudson, R. A. Pascal, Jr., and S. Bernhard, Accelerated Luminophore Discovery Through Combinatorial Synthesis, J. Am. Chem. Soc. 2004, 126, 14129-14135.

106. Huang, Q., M. L. Foo, R. A. Pascal, Jr., J. W. Lynn, B. H. Toby, Tao He, H. W. Zandbergen, and R. J. Cava, Coupling between electronic and structural degrees of freedom in the triangular lattice conductor NaxCO2, Phys. Rev. B 2004, 70, 184110.

107. Bewick, S. A., R. A. Pascal, Jr., D. M. Ho, Z. G. Soos, M. Masimo, and A. Girlando, Dipolar disorder in organic charge-transfer single crystals: Dipolar disorder in ClMePD-DMeDCNQI, J. Chem. Phys. 2005, 122, 024710.

108. Song, Q., D. M. Ho, and R. A. Pascal, Jr., A Sterically Congested In-Methylcyclophane, J. Am. Chem. Soc. 2005, 127, 11246-11247.

109. Walters, R. S., D. M. Ho, and R. A. Pascal, Jr., A Hydrogen Atom Sandwiched by Cyclopropanes, Tetrahedron Lett. 2005, 46, 6487-6489.

110. Song, Q., C. W. Lebeis, X. Shen, D. M. Ho, and R. A. Pascal, Jr., Polyphenyl Macrocyclic Oligophenylenes, J. Am. Chem. Soc. 2005, 127, 13732-13737.

111. Lowry, M. S., J. I. Goldsmith, J. D. Slinker, R. Rohl, R. A. Pascal, Jr., G. G. Malliaras, and S. Bernhard, Single-Layer Electroluminescent Devices and Photoinduced Hydrogen Production from an Ionic Iridium(III) Complex, Chem. Mater. 2005, 17, 5712-5719.

112. Pascal, R. A., Jr., Twisted Acenes, Chem. Rev. 2006, 106, 4809-4819.

113. Lee, M., L. Viciu, L. Li, Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, Jr., R. J. Cava, and N. P. Ong, Large enhancement of the thermopower in NaxCoO2 at high Na doping, Nature Materials 2006, 5, 537-540.

114. Schreiner, P. R., A. A. Fokin, R. A. Pascal, Jr., and A. de Meijere, Many Density Functional Theory Approaches Fail to Give Reliable Large Hydrocarbon Isomer Energy Differences, Org. Lett. 2006, 8, 3635-3638.

115. Lu, J., D. M. Ho, N. J. Vogelaar, C. M. Kraml, S. Bernhard, N. Byrne, L. R. Kim, and R. A. Pascal, Jr., Exceptionally Twisted Pentacenes, J. Am. Chem. Soc. 2006, 128, 17043-17050.

116. Song, Q., D. M. Ho, and R. A. Pascal, Jr., The Supertristeroids: Large, Chiral, Molecular Bowls Prepared by the Trimerization of Pentacyclic Steroidal Ketones, J. Org. Chem. 2007, 72, 4449-4453.

117. Pascal, R. A., Jr., C. M. Kraml, N. Byrne, and F. J. Coughlin, Computational and Experimental Studies of the Conformational Reactions of 1,3,5-Tris(pentaphenylphenyl)benzene, Tetrahedron 2007, 63, 11902-11910.

118. Coughlin, F. J., K. D. Oyler, R. A. Pascal, Jr., and S. Bernhard, Determination of Absolute Configuration of Chiral Hemicage Metal Complexes Using Time-Dependent Density Functional Theory, Inorg. Chem. 2008, 47, 974-979.

119. Lee, M., L. Viciu, L. Li, Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, Jr., R. J. Cava, and N. P. Ong, Enhancement of the thermopower in NaxCoO2 in the large-x regime (x > 0.75), Physica B 2008, 403, 1564-1568.

120. Pascal, R. A., Jr., and Q. Qin, Conformational Reactions of D2-Symmetric Twisted Acenes, Tetrahedron 2008, 64, 8630-8637.

121. Vavilala, C., N. Byrne, C. M. Kraml, D. M. Ho, and R. A. Pascal, Jr., Thermal C1-C5 Diradical Cyclization of Enediynes, J. Am. Chem. Soc. 2008, 130, 13549-13551.

122. Kumar, M., S. Ramasesha, R. A. Pascal, Jr., and Z. G. Soos, Dimerization transition of alkali-TCNQ salts: Charge degrees of freedom near the CDW boundary, Europhysics Letters 2008, 83, 37001.

123. Walters, R. S., C. M. Kraml, N. Byrne, D. M. Ho, Q. Qin, F. J. Coughlin, S. Bernhard, and R. A. Pascal, Jr., Configurationally Stable Longitudinally Twisted Polycyclic Aromatic Compounds, J. Am. Chem. Soc. 2008, 130, 16435-16441.

124. McQueen, T. M., D. M. Ho, C. Jimenez Cahua, R. J. Cava, R. A. Pascal, Jr., and Z. G. Soos, Realization of the bond order wave (BOW) phase of extended Hubbard models in Rb-TCNQ(II), Chem. Phys. Lett. 2009, 475, 44-48.

125. Soos, Z. G., M. Kumar, S. Ramasesha, and R. A. Pascal, Jr., 1:1 Alkali-TCNQ Salts and the Bond Order Wave (BOW) Phase of Half-filled Linear Hubbard-type Models, Physica B 2010, 405, S353-S356.

126. Qin, Q., J. T. Mague, and R. A. Pascal, Jr., An in-Ketocyclophane, Org. Lett. 2010, 12, 928-930.

127. Qin, Q., D. M. Ho, J. T. Mague, and R. A. Pascal, Jr., Exceptional Molecular Architectures via Cycloadditions to Pyrenequinones, Tetrahedron 2010, 66, 7933-7938.

128. Bai, X., C. Barnes, R. A. Pascal, Jr., X. Chen, and J. R. Dias, Bile Acid-Based Cage Compounds with Lipophilic Outer Shells and Inner Cavities, Org. Lett. 2011, 13, 3064-3067.

129. Kurtz, J., T. Grusenmeyer, L. Tong, G. Kosgei, R. H. Schmehl, J. T. Mague, and R. A. Pascal, Jr., Highly Luminescent, Polyaryl Mesobenzanthrones, Tetrahedron 2011, 67, 7211-7216.

130. Yang, Y., M. R. Mannion, L. N. Dawe, C. Kraml, R. A. Pascal, Jr., and G. J. Bodwell, Synthesis, Crystal Structure and Resolution of [10](1,6)Pyrenophane: an Inherently Chiral [n]Cyclophane, J. Org. Chem. 2012, 77, 57-67.

131. Pascal, R. A., Jr., C. M. Wang, G. C. Wang, and L. V. Koplitz, Ideal Molecular Conformation vs. Crystal Site Symmetry, Crystal Growth & Design 2012, 12, 4367-4376.

132. Sathyamoorthi, S., J. T. Mague, and R. A. Pascal, Jr., An in-Triphenylaminophane, Org. Lett. 2012, 14, 3427-3429.

133. Nandaluru, P. R., P. Dongare, C. M. Kraml, R. A. Pascal, Jr., L. N. Dawe, D. W. Thompson, and G. J. Bodwell, Concise, Aromatization-based Approach to a C2-Symmetric Pyrenophane, Chem. Commun. 2012, 48, 7747-7749.

134. Geng, X., J. T. Mague, and R. A. Pascal, Jr., Synthesis and Chiroptical Properties of Arylamines of Cholest-4-ene-3,6-dione, J. Org. Chem. 2012, 77, 10920-10924.

135. Zong, J., J. T. Mague, C. M. Kraml, and R. A. Pascal, Jr., A Congested in,in-Diphosphine, Org. Lett. 2013, 15, 2179-2181.

136. Pascal, R. A., Jr., and A. P. West, Jr., The Reliability and Utility of High Reported Specific Rotations: Reports and Predictions of Molecules with Extremely High Specific Rotations, and High Specific Rotations Suggest Revision of the Structures of Huperzines E' and F', Tetrahedron 2013, 69, 6108-6115.

137. Zong, J., J. T. Mague, and R. A. Pascal, Jr., Exceptional Steric Congestion in an in,in-Bis(hydrosilane), J. Am. Chem. Soc. 2013, 135, 13235-13237.

138. Zong, J., J. T. Mague, E. C. Welch, I. M. Eckert, and R. A. Pascal, Jr., Sterically Congested Macrobicycles with Heteroatomic Bridgehead Functionality, Tetrahedron 2013, 69, 10316-10321.

139. Pascal, R. A., Jr., J. Zong, K. J. Dougherty, X. Geng, and J. T. Mague, Experimental and Computational Studies of Molecules with Close, Non-Bonded Hydrogen-Hydrogen Contacts: Common Computational Methods Grossly Overestimate Some "Through-Space" NMR Scalar Coupling Constants, Tetrahedron 2014, 70, 7518-7526.

140. Dougherty, K. J., C. M. Kraml, N. Byrne, J. A. Porras, S. Bernhard, J. T. Mague, and R. A. Pascal, Jr., Helical Mesobenzanthrones: A Class of Highly Luminescent Helicenes, Tetrahedron 2015, 71, 1694-1699.

141. Geng, X., J. T. Mague, and R. A. Pascal, Jr., Tribenzodecacyclene and Hexabenzodecacyclene, J. Org. Chem. 2015, 80, 4824-4827.

142. Geng, X., J. P. Donahue, J. T. Mague, and R. A. Pascal, Jr., The Hairpin Furans: Easily Prepared Hybrids of Helicenes and Twisted Acenes, Angew. Chem. Int. Ed. 2015, 54, 13957-13960.

143. Geng, X., J. T. Mague, J. P. Donahue, and R. A. Pascal, Jr., Hairpin Furans and Giant Biaryls, J. Org. Chem. 2016, 81, 3838-3847.

144. Dougherty, K. J., J. T. Mague, L. J. Wilson, C. M. Kraml, and R. A. Pascal, Jr., A Chiral Bis-Anthraquinone-Bridged Cyclophane with a Large Specific Rotation, Tetrahedron: Asymmetry 2016, 27, 768-772.

145. Zong, J., J. T. Mague, and R. A. Pascal, Jr., In,in-Cyclophanes that Encapsulate Non-Hydrogen Atoms, Tetrahedron 2017, 73, 455-460.

146. Zhang, B., R. A. Pascal, Jr., Y. Zhao, and G. J. Bodwell, Generation of an Extremely Bent Pyrene System Using Kinetic Stabilization, Can. J. Chem. 2017, in press.