In colorimetry, metamerism is the matching of apparent color of objects with different spectral power distributions. Colors that match this way are called metamers.
A spectral power distribution describes the proportion of total light emitted, transmitted, or reflected by a color sample at every visible wavelength; it precisely defines the light from any physical stimulus. However, the human eye contains only three color receptors (cone cells), which means that all colors are reduced to three sensory quantities, called the tristimulus values. Metamerism occurs because each type of cone responds to the cumulative energy from a broad range of wavelengths, so that different combinations of light across all wavelengths can produce an equivalent receptor response and the same tristimulus values or color sensation.
Sources of metamerism
Metameric matches are quite common, especially in near neutral (grayed or whitish colors) or dark colors. As colors become lighter or more saturated, the range of possible metameric matches (different combinations of light wavelengths) becomes smaller, especially in surface colors.
Metameric matches made between two light sources provide the trichromatic basis of colorimetry. For any given light stimulus, regardless of the form of its spectral emittance curve, there always exists a unique mixture of three "primary" lights that when added together, or added to the stimulus, will exactly match it.
The basis for nearly all commercially available color image reproduction processes such as photography, television, printing, and digital imaging, is the ability to make metameric color matches.
Making metamerism matches using reflective materials is more complex. The appearance of surface colors is defined by the product of the spectral reflectance curve of the material and the spectral emittance curve of the light source shining on it. As a result, the color of surfaces depends on the light source used to illuminate them.
The term illuminant metameric failure is sometimes used to describe situations where two material samples match when viewed under one light source but not another. Most types of fluorescent lights produce an irregular or peaky spectral emittance curve, so that two materials under fluorescent light might not match, even though they are a metameric match to an incandescent "white" light source with a nearly flat or smooth emittance curve. Material colors that match under one source will often appear different under the other.
Normally, material attributes such as translucency, gloss or surface texture are not considered in color matching. However geometric metameric failure can occur when two samples match when viewed from one angle, but then fail to match when viewed from a different angle. A common example is the color variation that appears in pearlescent auto finishes or "metallic" paper; e.g., Kodak Endura Metallic, Fujicolor Crystal Archive Digital Pearl.
Observer metameric failure can occur because of differences in color vision between observers. The common source of observer metameric failure is colorblindness, but it is also not uncommon among "normal" observers. In all cases, the proportion of long-wavelength-sensitive cones to medium-wavelength-sensitive cones in the retina, the profile of light sensitivity in each type of cone, and the amount of yellowing in the lens and macular pigment of the eye, differs from one person to the next. This alters the relative importance of different wavelengths in a spectral power distribution to each observer's color perception. As a result, two spectrally dissimilar lights or surfaces may produce a color match for one observer but fail to match when viewed by a second observer.
Full article ▸