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If the reaction occurs
when insufficient oxygen is present, both carbon monoxide (CO) and carbon dioxide
(CO2) will be in the combustion products and the heat
released in the reaction will be reduced to Q'. When the fuel/air ratio differs
from that required for stoichiometric combustion, the combustion condition
can be described in terms of the "Equivalence Ratio."
Equivalence Ratio = (Actual Fuel/Air
ratio)/(Stoichiometric Fuel/air ratio) = f
If all of the heat of combustion
is converted into internal energy of the reaction products, their temperature
will increase to a value known as the "Adiabatic Flame
Temperature." In a real flame, heat losses and dissociation reactions
will reduce the flame temperature below the adiabatic value.
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