Etching
Index
Etching involves the selective removal of material from a sample by chemical or physical means. It is a "reverse growth" process in which surfaces of lowest energy tend to be the most stable and regions of lattice distortion tend to be more susceptible to removal. The technique is used to reveal the microstructure of sample surfaces. It is also employed to prepare surfaces for other treatments. Etching techniques include: Chemical etching, electrolytic etching, thermal etching, plasma etching, and preferential oxidation. The diagrams illustrate the effect of surface etching on surface texture and reflectivity, and show optical photomicrographs of the samples. The left diagram illustrates the effect of crystallite orientation on etched roughness and reflectivity. The right diagram illustrates preferential attack at grain boundaries and the local change in surface slope that this produces.
From: Callister, "Materials Science and Engineering," Wiley (1994)