Piezoelectric
Index
A piezoelectric material is one that develops an electrical potential diffence between its faces when subjected to an applied strain. The converse process also occurs and a piezoelectric material will change its dimensions when a voltage is applied to it. This behavior requires crystals which lack a center of symmetry. Displacing the free surfaces of the sample moves its constituent ions and creates an electric dipole moment in the material. The application of a voltage to the unstrained materail causes the relative displacement of the positive and negative sub-lattices of the structure and causes a strain in the material.

Crystalline quartz is a usefull piezoelectric material and is used as a source of elastic waves for testing materials. The material can also be excited at its resonant frequency and used as a stable oscillator.

Other ceramic materials such as barium titanate and lead titanate are good piezoelectrics. The barium titanate unit cell with the atoms in the polarized position is shown below. 

From:McMahon and Graham, 
"Introduction to Engineering Materials," 
Merion (1992)