Calculations:
We can see from the balanced equation that the stoichiometric
relationship between NaOH and KHP is 1:1. At the endpoint then:
(eqn.
1)
Remember that:
(eqn.
2)
and
(eqn.
3)
Substituting eqn. 2 and eqn.3 into eqn. 1 gives eqn. 4:
(eqn.
4)
Solving for Molarity NaOH, we obtain:
(eqn.
5)
Since the definition of Molarity is moles of solute per liter solution,
the volume of NaOH must be converted to liters.