Solids: Thermodynamics and Bonding

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Properties of Metallic Bonding

· The electron gas gives the material a high electrical and thermal conductivity.
· Free electrons make metals opaque and highly reflecting in the visible and infra-red; transparent in the ultraviolet.
· The non-specific nature of the bond allows many "impurity" atoms to be in the structure. Alloys are easily formed.
· The non-directional nature of the bond makes plastic deformation relatively easy.
· Typical binding energies (eV per atom): Na -> 1.1; Ag -> 3.0; Ni -> 4.4
· Crystal structure: Na -> bcc; Ag -> fcc; Ni -> fcc; Al -> fcc; Ti -> hcp; Fe -> bcc.
· Nearest neighbor distances: Na -> 0.37 nm; Ag -> 0.29 nm; Ni -> 0.25 nm; Ti: a = 0.29 nm, c = 0.47 nm; Fe -> 0.29 nm.
· Melting points (Celsius): Na -> 98.7; Ag -> 961; Ni -> 1453; Ti -> 1668