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Kinetics and Microstructural Control

· The solid phase has a concentration gradient between the center and the surface and its average composition follows the non-equilibrium solidus shown on the phase diagram.
· The final average composition of the solid must be the same as that of the initial liquid phase, Cu-40 wt % Ni, as matter is conserved.
· All phase transitions take place at a finite rate and involve the nucleation and growth of a new phase from an existing one.
· The stable phase at any temperature is that with the lowest Gibbs function and phases in equilibrium have the same Chemical Potential.
· An important issue in phase transformation will be the manner in which nucleation and growth takes place.
· Material property control of is possible since their temperature-time history determines their microstructure.