Solids: Thermodynamics and Bonding

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Permanent Dipoles

· Two examples of bonding due to permanent molecular dipoles are shown in the diagram.
· In both cases, the hydrogen component of the dipole has a positive charge because the electron distribution is more centered on the oxygen or fluorine components of the molecules.
· Because specific molecular locations are positive or negative, the bonding due to the dipolar interaction is directional.
· In ice, this directionality gives rise to many different crystal structures.

From: Moffatt, Pearsall, and Wulff, "The Structure and Properties of Materials," Wiley (1967)