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The Structure of Solids

BONDING AND CRYSTAL STRUCTURE

· Atoms are held together in a condensed phase by the interatomic potential. The nature of this potential is expected to influence the possible crystal structures of the solid.
· Three potentials, Metallic, Ionic, and van der Waals are non-directional. For potentials of this type the closest packing of atoms is expected to be favored taking into account the need for overall neutrality of the final structure and its chemical composition.
· The Covalent and Permanent Dipole potentials are directional, and distortion of the bond direction will increase the energy of the system. More open structures that reduce bond distortion might, therefore, be expected.