Corrosion & Environmental Degradation
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· Bone-plates are devices for strengthening a fractured bone during the healing process. The device is attached to the bone with metal screws, and is normally removed once satisfactory healing has occurred.
· In general, the relatively short period of use minimizes the importance of corrosion to the mechanical properties of the device. As suggested in the lower diagram, crevice corrosion in which the anodic regions are less exposed to the body fluids would contribute to mass loss.
· Stainless steel alloy containing 18% Cr and 8% Ni and a small percentage of Mo (Type 316) was an early choice. This alloy showed little corrosion on removal.
· If the steel has chromium carbide (Cr6C23) deposited in grain-boundary regions, this will deplete the adjacent material of chromium and give rise to electrolytic grain boundary corrosion.
· Care must also be taken that the materials used for the screws and the plates have the same composition and microstructure. Composition differences will give rise to galvanic cells and increased corrosion rates. Toxic reactions can then arise.